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Chemistry Compatibility

Chemistry Compatibility

Chemistry Compatibility

Product catalog summary
Introduction
This document provides an overview of the chemical compatibility and material specifications for VACUUBRAND chemistry diaphragm pumps. It focuses on the use of fluoropolymers and perfluoro elastomers, highlighting their chemical resistance and application in vacuum systems.
Material Specifications
  • PTFE (Polytetrafluoroethylene): Known for its outstanding chemical resistance, PTFE is not soluble in organic solvents and resists aggressive acids like aqua regia. It is used for its low material adhesion and high reliability.
  • ETFE (Ethylene Tetrafluoroethylene): A thermoplastic fluoropolymer with excellent mechanical properties, high tensile strength, and good chemical resistance. It is processed using molding techniques for dense, nonporous surfaces.
  • ECTFE (Ethylene Chlorotrifluoroethylene): Offers excellent chemical resistance and superior strength, wear, and creep resistance compared to PTFE. It is the most abrasion-resistant fluoropolymer available.
  • FFKM (Perfluoroelastomer): Provides ultimate performance in heat and chemical resistance, resisting over 1,800 chemicals. It is used in applications requiring high temperature stability and minimal process contamination.
Chemical Compatibility
The document includes a table summarizing the compatibility of various chemicals with PTFE, ETFE/ECTFE, and FFKM. The ratings are as follows:
  • ++: Excellent chemical resistance
  • +: Good to limited chemical resistance
  • –: Poor chemical resistance
Key chemicals and their compatibility include:
  • Acid amides: Excellent resistance across all materials.
  • Strong acids: Excellent resistance across all materials.
  • Alcohols and Aldehydes: Excellent resistance across all materials.
  • Bases: Excellent resistance across all materials.
  • Oxidizing agents: Varying resistance, with ECTFE showing limited resistance.
Design and Application
The document emphasizes the use of these materials in VACUUBRAND diaphragm pumps for their chemical resistance and low surface energy. The design includes:
  • Inlet and outlet flapper valves made of FFKM or PTFE for high leakage tightness.
  • Valve connectors made of ECTFE for optimal thermal, mechanical, and chemical resistance.
  • Head cover and clamping disc made of ETFE with a metal core for long-term performance.
  • PTFE sandwich diaphragms for increased reliability and extended service life.
Conclusion
VACUUBRAND utilizes fluoropolymers and perfluoro elastomers in their diaphragm pumps to ensure high chemical resistance and durability, making them suitable for various industrial applications.
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Catalog excerpts

Chemistry Compatibility-1

Head cover and clamping disc are made of thick walled molded ETFE with metal core for unsurpassed long-term performance Table for chemistry compatibility PTFE ETFE/ ECTFE Acid amides Acids, dilute or weak Acids, strong or concentrated Alcohols, aliphatic Hydrocarbons, aliphatic Hydrocarbons, aromatic Hydrocarbons, halogenated Oxidizing acids, oxidizing agents Dimethylformamide (DMF), Acetamide, Formamide Acetic acid, Carbonic acid, Butyric acid PTFE Well-proven PTFE sandwich diaphragms for increased reliability and extended service life Hydrochloric acid, Sulfuric acid, Nitric acid, Trifluoroacetic acid (TFA) Methanol, Ethanol, Butanol Formaldehyde, Ethanal, Hexanal N-Methyl-2-pyrrolidone (NMP), Triethylamine Sodium hydroxide, Potassium hydroxide, Ammonia FFKM Inlet and outlet flapper valves are made of FFKM or PTFE for both highest leakage tightness and best chemical resistance Ethyl acetate, Butyl formate, Amyl butyrate Diethyl ether, Tetrahydrofurane, Dioxane Pentane, Hexane, Heptane Benzene, Toluene, Xylene Methyl chloride, Chloroform, Ethylene chloride Acetone, Cyclohexanone Ozone, Hydrogen peroxide, Chlorine Valve connectors are made of ECTFE for an optimum of thermal, mechanical and chemical resistance Internal tubing and fittings made of PTFE/ETFE/ECTFE compounds Dimethyl sulfoxide (DMSO) P TFE: Polytetrafluoroethylene ETFE: Ethylene tetrafluoroethylene ECTFE: Ethylene chlorotrifluoroethylene FFKM: Perfluoro elastomer VACUUBRAND GMBH + CO KG Alfred-Zippe-Straße 4 97877 Wertheim Germany ++ excellent chemical resistance + good to limited chemical resistance – poor chemical resistance * for some solvents ‘+’ ©VACUUBRAND GMBH + CO KG . 05/2017 . EN/995512 . The data are based on information from various literature. VACUUBRAND does not warrant the accuracy of these data. Due to the variety of possible influencing factors, they can serve only as a guide. No legal claims may be derived from user reliance on these data. CHEMISTRY COMPATIBILITY of VACUUBRAND Chemistry Diaphragm Pumps

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Chemistry Compatibility-2

uncompromising chemistry design for diaphragm pumps One of the most distinguishing properties of PTFE is its outstanding chemical resistance, except for some extreme conditions such as molten alkali metals or elemental fluorine. Basically PTFE is not soluble in any organic solvents. Even aggressive acids such as aqua regia cannot attack PTFE. The reason for this is a particularly strong bond between the carbon and the fluorine atoms and the shielding of carbon atoms by the surrounding fluorine atoms. Fluoropolymers and perfluoro elastomers are materials containing fluorine atoms in their chemical...

 Open the catalog to page 2
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