S-412

S-412
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S-412

Product catalog summary
Identification of the Substance/Mixture and Company:
Product Identifier: S-412, used as dilutants for professional/industrial use. Supplier: Roberlo S.A.U., Spain. Emergency contact: +34 972 478060.
Hazards Identification:
The product is classified under CLP Regulation (EC) No 1272/2008 with hazards including flammable liquids, aspiration hazard, skin and eye irritation, and specific target organ toxicity. Hazard statements highlight risks of flammability, aspiration, skin and eye irritation, respiratory irritation, and environmental harm.
Composition/Information on Ingredients:
The mixture contains hazardous components such as 2-methoxy-1-methylethyl acetate and Xylene, each with specific concentration limits and hazard classifications.
First Aid Measures:
Inhalation: Move to fresh air and rest. Skin contact: Rinse with water and soap. Eye contact: Rinse with water for 15 minutes. Ingestion: Seek medical attention immediately, do not induce vomiting.
Firefighting Measures:
Use ABC powder, foam, or CO₂ extinguishers. Avoid full jet water. Firefighters should use protective clothing and SCBA.
Accidental Release Measures:
Isolate leaks, use personal protective equipment, and avoid environmental contamination. Absorb spills with inert material.
Handling and Storage:
Store in a cool, well-ventilated area away from ignition sources. Use protective equipment and follow safety regulations to prevent risks.
Exposure Controls/Personal Protection:
Monitor occupational exposure limits for components like Xylene and Ethylbenzene. Use appropriate personal protective equipment to minimize exposure.
Summary of Safety Data Sheet (SDS)
1. Introduction
This document is an English translation of the COMMISSION REGULATION (EU) 2020/878, providing safety data for various chemical substances without any country-specific legislation.
2. Exposure Controls/Personal Protection
  • Individual Protection Measures: Use basic Personal Protective Equipment (PPE) with CE marking as per Regulation (EU) 2016/425. This includes respiratory protection, hand protection, ocular and facial protection, body protection, and foot protection.
  • Respiratory Protection: Use filter masks for gases and vapours, replacing them when contaminants are detected inside the mask.
  • Hand Protection: Use chemical protective gloves made of Linear low-density polyethylene (LLDPE) with a breakthrough time of over 480 minutes.
  • Ocular and Facial Protection: Use panoramic glasses against splash/projections.
  • Body Protection: Wear antistatic and fireproof protective clothing and safety footwear with antistatic and heat-resistant properties.
  • Emergency Measures: Include emergency showers and eyewash stations.
3. Physical and Chemical Properties
  • Appearance: Liquid, colourless with a characteristic odour.
  • Volatility: Boiling point ranges from 125 - 218 ºC, with a vapour pressure of 656 Pa at 20 ºC.
  • Flammability: Flash point is 34 ºC, with an autoignition temperature of 287 ºC.
4. Stability and Reactivity
  • Reactivity: The product is stable under recommended storage conditions.
  • Chemical Stability: Stable under conditions of storage, handling, and use.
  • Conditions to Avoid: Avoid shock, friction, and direct sunlight.
  • Incompatible Materials: Avoid strong acids and alkalis.
  • Hazardous Decomposition Products: May release carbon dioxide, carbon monoxide, and other organic compounds under decomposition conditions.
5. Toxicological Information
  • Ingestion: May cause irritation, abdominal pain, nausea, and vomiting.
  • Inhalation: Causes irritation in respiratory passages.
  • Skin and Eye Contact: Produces skin inflammation and eye damage.
  • CMR Effects: No carcinogenicity or mutagenicity detected, but contains substances with reproductive toxicity.
  • Specific Target Organ Toxicity: High concentration exposure can affect the central nervous system, causing symptoms like headache, dizziness, and nausea.
Hazard Classifications:
  • Aspiration Toxicity (Asp. Tox. 1): May be fatal if swallowed and enters airways (H304).
  • Eye Irritation (Eye Irrit. 2): Causes serious eye irritation (H319).
  • Flammable Liquids (Flam. Liq. 2 & 3): Highly flammable liquid and vapour (H225); Flammable liquid and vapour (H226).
  • Reproductive Toxicity (Repr. 2): Suspected of damaging fertility or the unborn child (H361).
  • Skin Irritation (Skin Irrit. 2): Causes skin irritation (H315).
  • Specific Target Organ Toxicity - Repeated Exposure (STOT RE 2): May cause damage to organs through prolonged or repeated exposure via inhalation or oral routes (H373).
  • Specific Target Organ Toxicity - Single Exposure (STOT SE 3): May cause respiratory irritation (H335); May cause drowsiness or dizziness (H336).
Classification Procedures:
  • STOT SE 3, Aquatic Chronic 3, Skin Irrit. 2, STOT RE 2, Asp. Tox. 1, Flam. Liq. 3, Eye Irrit. 2: Calculation method.
Training Advice:

Minimal training is recommended to prevent industrial risks and to facilitate understanding of the safety data sheet and product label.

Principal Bibliographical Sources:
Abbreviations and Acronyms:
  • ADR: European agreement concerning the international carriage of dangerous goods by road
  • IMDG: International maritime dangerous goods code
  • IATA: International Air Transport Association
  • ICAO: International Civil Aviation Organisation
  • COD: Chemical Oxygen Demand
  • BOD5: 5-day biochemical oxygen demand
  • BCF: Bioconcentration factor
  • LD50: Lethal Dose 50
  • LC50: Lethal Concentration 50
  • EC50: Effective concentration 50
  • LogPOW: Octanol-water partition coefficient
  • Koc: Partition coefficient of organic carbon
  • UFI: Unique formula identifier
  • IARC: International Agency for Research on Cancer
Disclaimer:

The information is based on sources, technical knowledge, and current legislation at European and state levels. It is not a guarantee of product properties but a description of safety requirements. Users are responsible for ensuring compliance with legal requirements for handling, storage, use, and disposal of chemical products. The information pertains only to the specified product.

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Catalog excerpts

S-412-1

Safety data sheet This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific legislation SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier: Other means of identification: UFI: 1.2 Relevant identified uses of the substance or mixture and uses advised against: Relevant uses: Dilutants. For professional users/industrial user only. Uses advised against: All uses not specified in this section or in section 7.3 Details of the supplier of the safety data sheet: Roberlo S.A.U. Ctra. Nacional II, Km. 706,5 17457 Riudellots de la Selva - Gerona - España Phone: +34 972 478060 (8:00-12:45 / 14:15-17:30 h) ROBERLO (España) (GMT +1:00) - Fax: +34972477394 [email protected] Emergency telephone number: +34 972 478060 (8:00-12:45 / 14:15-17:30 h) ROBERLO (Spain) (GMT + 1:00) SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture: CLP Regulation (EC) No 1272/2008: Classification of this product has been carried out in accordance with CLP Regulation (EC) No 1272/2008. Aquatic Chronic 3: Hazardous to the aquatic environment, long-term hazard, Category 3, H412 Asp. Tox. 1: Aspiration hazard, Category 1, H304 Eye Irrit. 2: Eye irritation, Category 2, H319 Flam. Liq. 3: Flammable liquids, Category 3, H226 Skin Irrit. 2: Skin irritation, Category 2, H315 STOT RE 2: Specific target organ toxicity — Repeated exposure, Hazard Category 2 (Oral), H373 STOT SE 3: Specific toxicity causing drowsiness and dizziness, single exposure, Category 3, H336 STOT SE 3: Respiratory tract toxicity, single exposure, Category 3, H335 Label elements: CLP Regulation (EC) No 1272/2008: Danger Hazard statements: H226 - Flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H336 - May cause drowsiness or dizziness. H373 - May cause damage to organs through prolonged or repeated exposure (Oral). H412 - Harmful to aquatic life with long lasting effects. Precautionary statements: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280: Wear protective gloves/protective clothing/respiratory protection/eye protection/protective footwear. P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor. P302+P352: IF ON SKIN: Wash with plenty of water. P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370+P378: In case of fire: Use ABC powder extinguisher to extinguish. P501: Dispose of contents/container in accordance with regulations on hazardous waste or packaging and packaging waste respectively. Substances that contribute to the classification - CONTINUED ON NEXT PAGE Date of compilation: 01/03/2022

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S-412-2

Safety data sheet This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific legislation SECTION 2: HAZARDS IDENTIFICATION (continued) 2-methoxy-1-methylethyl acetate; Xylene; 1-methoxy-2-propanol; Hydrocarbons, C9, aromatics UFI: 2.3 Other hazards: Product fails to meet PBT/vPvB criteria Endocrine-disrupting properties: The product fails to meet the criteria. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substance: Non-applicable Mixture: Chemical description: Solvent/s Components: In accordance with Annex II of Regulation (EC) No 1907/2006...

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S-412-3

Safety data sheet This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific legislation SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS (continued) Identification Specific concentration limit SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures: The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct exposure to the chemical product or persistent discomfort, showing the SDS of this product. By inhalation: Remove the person affected from the area of exposure,...

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S-412-4

Safety data sheet This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific legislation SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures: For non-emergency personnel: Isolate leaks provided that there is no additional risk for the people performing this task. Evacuate the area and keep out those without protection. Personal protection equipment must be used against potential contact with the spilt product (See section 8). Above all prevent the formation of any vapour-air flammable mixtures,...

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S-412-5

Safety data sheet This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific legislation SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued) 8.1 Control parameters: Substances whose occupational exposure limits have to be monitored in the workplace (European OEL, not country-specific legislation): Directive (EU) 2000/39, Directive 2004/37/EC,Directive (EU) 2006/15, Directive (EU) 2009/161, Directive (EU) 2017/164, Directive (EU) 2019/1831: Identification Occupational exposure limits IOELV (STEL) IOELV (STEL) IOELV (STEL) IOELV (STEL) IOELV...

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S-412-6

Safety data sheet This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific legislation SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued) Short exposure Identification Long exposure Systemic Hydrocarbons, C10, aromatics, < 1% naphthalene N-butyl acetate Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) N-butyl acetate Fresh water Marine water Sediment (Fresh water) Sediment...

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