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Material Safety Data Sheet Sealed Lead Acid Batteries (MSDS)

Material Safety Data Sheet Sealed Lead Acid Batteries (MSDS)

Material Safety Data Sheet Sealed Lead Acid Batteries (MSDS)

Product catalog summary
Product Identification
This document is a Material Safety Data Sheet (MSDS) for Power-Sonic's Valve Regulated Lead Acid (VRLA) Batteries, specifically the PS, PSH, PSG, and PG models with absorbed electrolyte (AGM). The information is provided for customer safety and is accurate as of January 25, 2010.
Hazardous Ingredients
The main components include inorganic lead/lead compounds (65%-75%), tin (<0.5%), calcium (<0.1%), sulfuric acid (14-20%), fiberglass separator (5%), and acrylonitrile butadiene styrene (ABS) (5-10%). Lead and sulfuric acid are the primary hazardous materials.
Physical/Chemical Characteristics
Lead is a silver-gray metal with a melting point of 621°F. Sulfuric acid is a clear, colorless liquid with a pungent odor, fully soluble in water. The fiberglass separator is a white fibrous material.
Flammability Data
Lead and sulfuric acid have no flashpoint or explosive limits. Hydrogen gas may be emitted if batteries are overcharged. Fiberglass and ABS may release toxic vapors or combustible gases at high temperatures.
Reactivity Data
Sulfuric acid is stable but reacts violently with combustibles and certain chemicals, potentially releasing toxic gases. Lead compounds should avoid contact with strong acids and bases.
Health Hazard Data
Exposure to sulfuric acid can cause severe respiratory, skin, and eye irritation. Lead compounds can cause respiratory issues and are toxic if ingested. Chronic exposure to lead affects the kidneys and nervous system.
Precautions for Safe Handling and Use
In case of spills, contain and neutralize with non-combustible materials. Store batteries in a cool, dry, ventilated area away from incompatible materials. Use insulated tools to prevent short circuits.
Control Measures
Under normal conditions, no special respiratory or protective equipment is needed. Damaged batteries require acid-resistant clothing and eye protection.
Regulatory Information
Power-Sonic batteries are classified as non-restricted for transportation under U.S. DOT and international regulations, provided they pass specific vibration and pressure tests. They are marked as "NON-SPILLABLE" and comply with various international standards.
Regulatory Overview
Acid batteries are not classified as hazardous waste by the EPA when recycled, but state and international regulations may differ.
CERCLA and EPCRA Regulations
  • Reportable Quantity (RQ): For 100% sulfuric acid spills, the RQ under CERCLA and EPCRA is 1,000 lbs. State and local RQs may vary.
  • Extremely Hazardous Substance: Sulfuric acid is listed under EPCRA with a Threshold Planning Quantity (TPQ) of 1,000 lbs.
  • EPCRA Section 302 Notification: Required if 1,000 lbs. or more of sulfuric acid is present at a site.
  • EPCRA Section 312 Tier 2 Reporting: Required for batteries if sulfuric acid is present in quantities of 500 lbs. or more and/or lead is present in quantities of 10,000 lbs. or more.
  • Supplier Notification: The product contains toxic chemicals reportable under EPCRA Section 313. Relevant for manufacturing facilities under SIC codes 20-39.
Regulatory Information
  • Toxic Chemicals:
    • Lead (CAS 7439-92-1): Approx. 60% by weight
    • Sulfuric Acid (CAS 7664-93-9): 10-30% by weight
    • Arsenic (CAS 7440-38-2): 0.2% by weight
  • Information must be provided with the first shipment in a calendar year if distributed to manufacturers in SIC codes 20-39. The Section 313 supplier notification does not apply to consumer product batteries.
TSCA Registry
Ingredients in Power-Sonic Corporation’s batteries are listed in the TSCA Registry, including sulfuric acid, lead compounds, arsenic, calcium, and tin.
Contact Information
Power-Sonic Corporation can be contacted via email at [email protected] or through their website at http://www.power-sonic.com.
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Catalog excerpts

Material Safety Data Sheet Sealed Lead Acid Batteries (MSDS)-1

Power-Sonic MSDS Page 1 of 6 Continued on next page MATERIAL SAFETY DATA SHEET PS, PSH, PSG and PG Valve Regulated (VRLA) Batteries Absorbed Electrolyte (AGM) Section 1 - Product Identification The information contained within is provided as a service to our customers and is for their information only. The information and recommendations set forth herein are made in good faith and are believed to be accurate at the date compiled. Power-Sonic Corporation makes no warranty expressed or implied. Section 2 - Hazardous Ingredients/Identity Information Components CAS Number Approx Wt. % OSHA PEL (4g/m³) ACGIH TLV (4g/m³) NIOSH (4g/m³) Inorganic Lead/Lead Compounds 7439-92-1 65%-75% 50 150 10 Tin 7440-31-5 <0.5% 2000 2000 N/A Calcium 7440-70-2 <0.1% N/A N/A N/A Electrolyte: Dilute sulfuric Acid 7664-93-9 14-20% 1000 1000 1000 Fiberglass Separator - 5% N/A N/A N/A Case Material: Acrylonitrile Butadine Styrene (ABS) 9003-56-9 5-10% N/A N/A N/A Inorganic lead and electrolyte (sulfuric acid) are the main components of every Valve Regulated Lead Acid battery supplied by Power-Sonic Corporation. Other ingredients may be present dependent upon the specific battery type. For additional information contact Power-Sonic Corporation Technical Department. Section 3 - Physical/Chemical Characteristics Components Density Melting Points Solubility (H2O) Odor Appearance Lead 11.34 621 °F None None Silver-Gray Lead Sulfate 6.20 1950 °F 40mg/l (60 °F) None White Powder Lead Dioxide 9.40 554 °F None None Brown Powder Sulfuric Acid About 1.30 203-240 °F 100% Sharp penetrating pungent Clear Colorless Liquid Fiberglass Separator N/A N/A Slight None White Fibrous Case Material: Acrylonitrile Butadine Styrene (ABS) N/A N/A None None Solid Manufacturers Name Power-Sonic Corporation, 7550 Panasonic Way San Diego, CA 92154 Emergency Telephone Numbers: CHEMTREC (Domestic): (800) 424-9300 CHEMTREC (International): (703) 527-3887 Telephone Number for Information Power-Sonic Corporation: (619) 661-2020 Date Issued: January 25, 2010

 Open the catalog to page 1
Material Safety Data Sheet Sealed Lead Acid Batteries (MSDS)-2

Power-Sonic MSDS Page 2 of 6 Continued on next page Section 4 – Flammability Data Components Flashpoint Explosive Limit Comments Lead and Sulfuric Acid None None None Hydrogen LEL = 4.1% Sealed batteries can emit hydrogen if overcharged (float voltage> 2.40 VPC) Fiberglass Separator N/A N/A Toxic vapors may be released. In case of fire, wear self contained breathing apparatus Acrylonitrile Butadine Styrene (ABS) None N/A Temp over 527°F (300°C) may release combustible gases. In case of fire, wear self contained breathing apparatus Section 5 - Reactivity Data Section 6 - Health Hazard Data Routes...

 Open the catalog to page 2
Material Safety Data Sheet Sealed Lead Acid Batteries (MSDS)-3

Power-Sonic MSDS Page 3 of 6 Continued on next page Ingestion Sulfuric acid: May cause severe irritation of the mouth, throat, esophagus, and stomach. Lead compounds: May cause abdominal pain, nausea, vomiting, diarrhea, and severe cramping. Acute ingestion should be treated by a physician. Eye Contact Sulfuric acid: Severe irritation, burns, cornea damage and possible blindness. Lead Compounds: May cause eye irritation. Acute Health Hazards Sulfuric acid: Severe skin irritation, burns, damage to cornea may cause blindness, upper respiratory irritation. Lead compounds: May cause abdominal pain,...

 Open the catalog to page 3
Material Safety Data Sheet Sealed Lead Acid Batteries (MSDS)-4

Power-Sonic MSDS Page 4 of 6 Continued on next page Section 7 - Precautions for Safe Handling and Use Steps to be Taken in Case Material is Released or Spilled There is no release of material unless the case is damaged or battery is misused/overcharged. If release occurs stop flow of material, contain/absorb all spills with dry sand, earth, or vermiculite. Do not use combustible materials. Neutralize spilled material with soda ash, sodium bicarbonate, lime, etc. Wear acid-resistant clothing, boots, gloves, and face shield. Dispose of as hazardous waste. Do not discharge acid to sewer Waste Disposal...

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Material Safety Data Sheet Sealed Lead Acid Batteries (MSDS)-5

Power-Sonic MSDS Page 5 of 6 Continued on next page Section 9 Regulatory Information NFPA Hazard Rating for Sulfuric Acid Transportation Batteries. Non-Restricted Status Shipment of Power-Sonic Rechargeable Sealed Lead Acid Batteries NORTH AMERICA – SURFACE AND AIR SHIPMENTS Non-Restricted Status Our non-spillable lead acid batteries are listed in the U.S. Department of Transportation (DOT) hazardous materials regulations, but are excepted from these regulations since they met all of the following requirements found under 49 CFR 173.159 and 49 CFR 173.159(a) 49 CFR 173.159: (f) Batteries can...

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Material Safety Data Sheet Sealed Lead Acid Batteries (MSDS)-6

Power-Sonic MSDS Page 6 of 6 Shipment of Power-Sonic Rechargeable Sealed Lead Acid Batteries INTERNATIONAL Non-Restricted Status Our non-spillable lead acid batteries also are excepted from the international hazardous materials (also known as “dangerous goods”) regulations since they comply with the following requirements: • The vibration and pressure differential tests found in Packing Instruction 806 and Special Provision A67 of the International Air Transport Association (IATA) Dangerous Goods Regulations; • The vibration and pressure differential tests found in Packing Instruction 806 and...

 Open the catalog to page 6

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*Prices are pre-tax. They exclude delivery charges and customs duties and do not include additional charges for installation or activation options. Prices are indicative only and may vary by country, with changes to the cost of raw materials and exchange rates.