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Getting It Right in Filled Polymer Extrusion

Getting It Right in Filled Polymer Extrusion

Getting It Right in Filled Polymer Extrusion

Product catalog summary
Introduction
The document discusses screw design for processing thermoplastic composites, focusing on the impact of fillers and additives on screw performance and equipment wear.

Screw Design
Feeding the Polymer: The addition of fillers alters the coefficient of friction (COF), affecting the screw's solids conveying performance. Adjustments in screw design and temperature profiles may be necessary to maintain feed pressure and prevent process surging.
Melting the Polymer: Fillers increase resin density, requiring adjustments in the screw's volumetric compression ratio. Barrier-type screws must accommodate non-compressible fillers to prevent pressure differentials and temperature overrides.
Pumping the Polymer: Consistent output is crucial. Fillers increase viscosity, aiding pumping but potentially causing higher head pressure if the die is not designed for viscous compounds.

Barrel Temperature Override
Temperature overrides occur due to viscous heating when processing filled resins with screws designed for unfilled resins. Adjusting barrel zone temperatures can temporarily alleviate this, but long-term solutions require proper screw design.

Wear
Screw Wear: Fillers cause abrasive wear, particularly in the feed section. Methods to reduce wear include nitriding, J-groove welding, and tungsten-carbide coatings.
Barrel Wear: Bimetallic liners with tungsten-carbide particles enhance barrel durability, extending life and allowing higher screw speeds.

Conclusion
Proper screw design and construction are essential for successful processing of thermoplastic composites. Early research and planning can reduce the learning curve and improve processing outcomes.

References
The document cites several references on polymer extrusion and processing principles.
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Catalog excerpts

Getting It Right in Filled Polymer Extrusion -1

ByTimothy W. WomerXaloy Inc. Introduction There are two different areas of screw designfor thermoplastic composites: the screwdesign which is being used to make thethermoplastic compound and the screwdesign which is used to process thecompounded thermoplastic. This papermainly discusses the latter of the two types,but many of the issues are pertinent to both.The use of various fillers and additives,which are compounded into thermoplasticresins, has become more and more prevalentin recent years in the plastics industry. Theaddition of fillers such as talc, mica, calciumcarbonate and nanoclays can increase thestiffness and/or strength and the utilization ofvarious plastics. These fillers have also hadan effect on the performance and life of theequipment that processes them. This paperwill discuss some of the issues that thesecomposites have on the screw design, plusscrew and barrel wear. Screw Design Most screws used in the extrusion ofthermoplastic resins primarily deal with theissues of feeding, melting and pumping of theresin. Feeding the Polymer Melting the Polymer In the feed section of the screw where solidsconveying takes place, the feedingmechanism for a thermoplastic compositemay be quite different from that of the verysame thermoplastic polymer without filler. In the solids conveying function of thescrew, the most critical phenomenon is therelative coefficient of friction (COF) of thepolymer. In the feed section there are threedifferent coefficients of friction at work: theCOF between the pellet and the barrel wall,the COF between the pellet and the screwroot and the COF between pellet and pellet.Although a given polymer may feed verywell in the in the neat, or unfilled, state, theaddition of fillers often causes aconsiderable change in its COF and,therefore, in the screws solids conveyingperformance. For example, any time micais the filler or additive in the base material,the COF drops dramatically. Therefore, thescrew may need to have a longer feedsection of constant depth in order to developenough feed pressure before material entersthe transition section or barrier section.Also, to enhance the solids conveying ofsuch a material, it might require changingthe temperature profile by raising thetemperature in the first barrel zone toincrease the COF between the pellet and thebarrel wall. This would allow the polymerto start to tackify or stick to the barrel so thatit can be conveyed forward. Poor orunstable solids conveying will translatedirectly into low throughput rates and causesignificant surging of the process. The most important aspect of screwgeometry affecting melting is the volumetriccompression ratio. This is determined by thechange in channel volume that takes place in >

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Getting It Right in Filled Polymer Extrusion -2

the transition section or barrier section of thescrew, which is typically located directlyafter the feed section of the screw.When fillers are added to resins, it increasestheir specific gravity. For example, a neat,or unfilled, 2 MFR polypropylene has aspecific gravity of 0.92, whereas the samepolymer with 40% talc filler has a specificgravity of 1.24. This is an increase of 35% indensity and also a 40% reduction in theamount of polymer that needs to be meltedduring processing. Since the filler is takingup volume in the screw channels and doesnot melt, compensations must be made inscrew design.As...

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Getting It Right in Filled Polymer Extrusion -3

Normally, the first processing technique thatshould be used is to increase all of the barrelzones prior to the zone that is overriding.This should help raise the temperature of theresin, lower its viscosity and in turn allow itto flow more easily through the portion of thescrew where the temperature override washappening. In most cases, this is only atemporary fix, and a long-term solution needsto be implemented with a properly designedscrew.By correcting the screw design so that thegeometry takes into account the amount offiller in the thermoplastic compound,temperature overrides can be eliminated,...

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Getting It Right in Filled Polymer Extrusion -4

when it does, the composite thermoplasticwill erode away the base metal like a hotknife through butter.Ӕ The problem with thisis that the operator will not be able to tellwhen this will happen unless that screw ispulled from the extruder on a regular basisand visually examined.This type of wear is repairable. The onlyproblem will be at the area where the newlywelded material meets the original base metalthat has been nitrided because many pinholeswill appear. These are caused by nitridinggases boilingӔ out of the base metal duringthe welding procedure. There is basicallynothing that can be done...

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Getting It Right in Filled Polymer Extrusion -5

All of the mentioned forms of screwprotection will have additional costs to thepurchase of the new screw, but the extendedand consistent longevity they provide greatlyoutweigh their initial cost. Conclusion Barrel Wear When extruding thermoplastic compositematerials, screw design and screw and barrelconstruction are crucial considerations. Ifthey are addressed properly up front, theprocessing of thermoplastic compositematerials will be successful.The main lesson to learn here is that if theproper research is done up front whenconsidering processing thermoplasticcomposite materials, the learning...

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