Information for the safe handling of Lead-Acid batteries
Information for the safe handling of Lead-Acid batteries
- Article: Lead-acid battery
- Relevant Uses: Starter batteries for vehicles, industrial batteries for motive power and standby applications
- Manufacturer: MIDAC S.p.A., Soave, Italy
- Contact: [email protected]
- Emergency Numbers: Italy: +39 0382 24444, Other countries: National poison control centers
- Explosion Hazard: Avoid smoking, open flames, and sparks near batteries due to oxyhydrogen gas during charging.
- Corrosive Hazard: Contains sulphuric acid, harmful to skin and eyes.
- Electrical Hazard: Risk of electrical shock from high current.
- Health Hazard: Lead compounds are harmful if swallowed or inhaled.
- Lead Metal and Compounds: 60-70%, harmful to health and environment.
- Sulphuric Acid Solution: 30-40%, causes severe skin burns.
- Thermoplastic Polymers: 6-9%, non-hazardous.
- Inhalation: Move to fresh air, seek medical advice if respiratory issues occur.
- Skin Contact: Wash with water, remove contaminated clothing, seek medical advice if irritation persists.
- Eye Contact: Rinse with water, seek medical advice immediately.
- Swallowing: Rinse mouth, drink water, do not induce vomiting, seek medical advice.
- Suitable Extinguishers: Dry powder, foam, CO2.
- Incorrect Extinguishers: Avoid water due to exothermic reaction with acid.
- Personal Precautions: Wear PPE to avoid contact with electrolyte.
- Environmental Measures: Prevent electrolyte from entering water sources.
- Cleaning Methods: Neutralize with sodium or calcium carbonate, use absorbent materials.
- Store in cool, ventilated areas away from heat and flames.
- Use PPE such as rubber gloves, safety glasses, and anti-acid overalls.
- Solid state, prismatic shape, corrosive, non-flammable.
- Stable and non-reactive under normal conditions.
- Electrolyte and lead compounds are harmful to the environment.
- Classified as hazardous waste, must be disposed of through authorized centers.
- Non-hazardous if shipped dry charged.
- Specific regulations for flooded and VRLA batteries by land, sea, and air.
- Contains substances of very high concern (SVHC) under REACH regulation.
The document discusses the presence of Substances of Very High Concern (SVHC) in batteries, specifically focusing on lead metal and lead monoxide. The content of lead metal in the batteries always exceeds the notification threshold of 0.1% by weight. Dry-charged batteries contain lead monoxide, which also exceeds 0.1% by weight. Upon adding electrolyte, lead monoxide transforms into lead sulphate, which is not classified as an SVHC.
The information provided is accurate to the best of the issuer's knowledge at the time of release. It pertains specifically to the described product and does not guarantee product quality or performance. Users are responsible for assessing the suitability and accuracy of the information for their specific battery applications.
Catalog excerpts
MIDAC S.p.A. CERTIFIED MANAGEMENT SYSTEM ISO 9001 - ISO 14001 - ISO 45001 Via A. Volta, 2 - Z.I. - 37038 SOAVE (Verona) ITALIA - Tel. +39 045 6132 132 - Fax +39 045 6132 133 Codice Fiscale e C.C.I.A.A. VR 02103180242 - Partita Iva IT 02103180242 - R.E.A. VR n.225330 Iscrizione C.C.I.A.A. VR: R.P.A. IT09060P00000483 - R.A.E.E. IT21020000012757 Capitale Sociale EURO 20.000.000,00 i.v. – e-mail: [email protected] – www.midacbatteries.com Information for the safe handling of Lead-Acid batteries The Lead-acid battery is not a “substance”, a mixture or a dangerous “preparation” according to Regulation (EC) no. 1907/2006, it is an “article”; no substance is intended to be released during the utilization. There is no obligation, therefore, to provide a safety data sheet in accordance with the Regulation (EC) no. 1907/2006, article 31 and related Annex II (as amended by Regulation (EU) 2020/878). This document, however, is made available to recipients and consumers in compliance with the provisions of Regulation (EC) no. 1907/2006, article 33. 1. Article identification and manufacturer 1.1 Article: Lead-acid battery 1.2 Relevant uses: Starter batteries for cars and vehicles Industrial batteries for motive power and standby applications 1.3 Manufacturer: MIDAC S.p.A. Via Alessandro Volta, 2 – 37038 Soave (VR) - Italy Telephone +39 045.61.32.132 Fax +39 045.61.32.133 E-mail address of the competent person responsible for the present document: [email protected] 1.4 Emergency telephone numbers: ITALY: Pavia - Poison Center, +39 0382 24444 OTHER COUNTRIES: Poison control national center 2. Safety warnings and hazards Using correctly intact battery, do not exist special hazards to humans and the environment. Explosion Hazard: An explosive mixture of oxyhydrogen gas occurs when charging batteries. Therefore, do not smoke, do not use naked flames or fires, and do not cause sparks in the immediate vicinity of the battery. Avoid short-circuits in the battery terminals. Always use anti-static materials when cleaning. Do not store the battery in sealed containers; always store in a cool and well-ventilated area away from direct sunlight and heat sources. Corrosive Hazard: Lead-acid batteries contain sulphuric acid diluted in a water solution which is corrosive and harmful to skin and eyes. Specific gravity 1.22 ÷ 1.30 kg/l (30 – 40 %). SdS-Pb-EN rev. 13 – 13/02/2024 1 di 7 Direzione e co
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CERTIFIED MANAGEMENT SYSTEM ISO 9001 - ISO 14001 - ISO 45001 Via A. Volta, 2 - Z.I. - 37038 SOAVE (Verona) ITALIA - Tel. +39 045 6132 132 - Fax +39 045 6132 133 Codice Fiscale e C.C.I.A.A. VR 02103180242 - Partita Iva IT 02103180242 - R.E.A. VR n.225330 Iscrizione C.C.I.A.A. VR: R.P.A. IT09060P00000483 - R.A.E.E. IT21020000012757 Capitale Sociale EURO 20.000.000,00 i.v. - e-mail: [email protected] - www.midacbatteries.com Lead-acid batteries can contain a considerable amount of energy, which may be a source of high electrical current and a severe electrical shock in the event of a short...
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MIDAC S.p.A. CERTIFIED MANAGEMENT SYSTEM ISO 9001 - ISO 14001 - ISO 45001 Via A. Volta, 2 - Z.I. - 37038 SOAVE (Verona) ITALIA - Tel. +39 045 6132 132 - Fax +39 045 6132 133 Codice Fiscale e C.C.I.A.A. VR 02103180242 - Partita Iva IT 02103180242 - R.E.A. VR n.225330 Iscrizione C.C.I.A.A. VR: R.P.A. IT09060P00000483 - R.A.E.E. IT21020000012757 Capitale Sociale EURO 20.000.000,00 i.v. – e-mail: [email protected] – www.midacbatteries.com a) Inhalation: Probability of exposure by inhalation is low, however in the event this should occur move the injured person away from the contaminated area...
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MIDAC S.p.A. CERTIFIED MANAGEMENT SYSTEM ISO 9001 - ISO 14001 - ISO 45001 Via A. Volta, 2 - Z.I. - 37038 SOAVE (Verona) ITALIA - Tel. +39 045 6132 132 - Fax +39 045 6132 133 Codice Fiscale e C.C.I.A.A. VR 02103180242 - Partita Iva IT 02103180242 - R.E.A. VR n.225330 Iscrizione C.C.I.A.A. VR: R.P.A. IT09060P00000483 - R.A.E.E. IT21020000012757 Capitale Sociale EURO 20.000.000,00 i.v. – e-mail: [email protected] – www.midacbatteries.com 8. Exposure control/personal protection Except for safety shoes, all other PPE (personal protective equipment) are for protection against exposure to electrolyte...
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MIDAC S.p.A. CERTIFIED MANAGEMENT SYSTEM ISO 9001 - ISO 14001 - ISO 45001 Via A. Volta, 2 - Z.I. - 37038 SOAVE (Verona) ITALIA - Tel. +39 045 6132 132 - Fax +39 045 6132 133 Codice Fiscale e C.C.I.A.A. VR 02103180242 - Partita Iva IT 02103180242 - R.E.A. VR n.225330 Iscrizione C.C.I.A.A. VR: R.P.A. IT09060P00000483 - R.A.E.E. IT21020000012757 Capitale Sociale EURO 20.000.000,00 i.v. – e-mail: [email protected] – www.midacbatteries.com a) FLOODED LEAD-ACID BATTERIES By land (ADR/RID - road/railway): Proper Shipping Name: BATTERIES, WET, FILLED WITH ACID electric storage UN2794 8 Not assigned...
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MIDAC S.p.A. CERTIFIED MANAGEMENT SYSTEM ISO 9001 - ISO 14001 - ISO 45001 Via A. Volta, 2 - Z.I. - 37038 SOAVE (Verona) ITALIA - Tel. +39 045 6132 132 - Fax +39 045 6132 133 Codice Fiscale e C.C.I.A.A. VR 02103180242 - Partita Iva IT 02103180242 - R.E.A. VR n.225330 Iscrizione C.C.I.A.A. VR: R.P.A. IT09060P00000483 - R.A.E.E. IT21020000012757 Capitale Sociale EURO 20.000.000,00 i.v. – e-mail: [email protected] – www.midacbatteries.com By sea (IMDG Code): Proper Shipping Name: BATTERIES, WET, NON SPILLABLE electric storage UN2800 8 Not assigned P003 F-A, S-B No. 8 IMDG UN No.: IMDG Hazard...
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MIDAC S.p.A. CERTIFIED MANAGEMENT SYSTEM ISO 9001 - ISO 14001 - ISO 45001 Via A. Volta, 2 - Z.I. - 37038 SOAVE (Verona) ITALIA - Tel. +39 045 6132 132 - Fax +39 045 6132 133 Codice Fiscale e C.C.I.A.A. VR 02103180242 - Partita Iva IT 02103180242 - R.E.A. VR n.225330 Iscrizione C.C.I.A.A. VR: R.P.A. IT09060P00000483 - R.A.E.E. IT21020000012757 Capitale Sociale EURO 20.000.000,00 i.v. – e-mail: [email protected] – www.midacbatteries.com Where applicable, to make reference to normative following: - D. Lgs. 152/2006 and following modifications; - D. Lgs. 81/2008 and following modifications;...
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