Carbon Dioxide -CO2
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Carbon Dioxide -CO2 - 1

Safety data sheet Carbon dioxide, refrigerated liquid. Creation date : Revision date : 27.01.2005 20.12.2010 Version : 2.0 DE / E 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY P403 Product name Carbon dioxide, refrigerated liquid. Trade name Carbon dioxide liquified EC No (from EINECS): 204-696-9 CAS No: 124-38-9 Index-Nr. Chemical formula CO2 REACH Registration number: Listed in Annex IV/V of Regulation (EC) No 1907/2006 (REACH), exempted from registration. Known uses Not known. Company identification Linde AG, Linde Gas Division, Seitnerstraße 70, D-82049 Pullach E-Mail Address Info@de.linde-gas.com Emergency phone numbers (24h): 089-7446-0 SDS No. : 9451 page 1 / 3 Precautionary Statement Disposal 2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification acc. to Regulation (EC) No 1272/2008/EC (CLP/GHS) Press. Gas - Contains refrigerated gas; may cause cryogenic burns or injury. Classification acc. to Directive 67/548/EEC & 1999/45/EC Not classified as hazardous to health. Asphyxiant in high concentrations. Risk advice to man and the environment Refrigerated liquefied gas. Contact with productmay cause cold burns or frostbite. Label Elements - Labelling Pictograms - Signal word Warning - Hazard Statements H281 EIGA-As Contains refrigerated gas; may cause cryogenic burns or injury. Asphyxiant in high concentrations. - Precautionary Statements Precautionary Statement Prevention P282 Wear cold insulating gloves/face shield/eye protection. Precautionary Statement Reaction P336+P315 Thaw frosted parts with lukewarm water. Do no rub affected area. Get immediate medical advice/attention. Precautionary Statement Storage 3 Store in a well-ventilated place. COMPOSITION/INFORMATION ON INGREDIENTS Substance/Preparation: Substance. Components/Impurities Carbon dioxide, refrigerated liquid. CAS No: 124-38-9 Index-Nr.: EC No (from EINECS): 204-696-9 REACH Registration number: Listed in Annex IV/V of Regulation (EC) No 1907/2006 (REACH), exempted from registration. Contains no other components or impurities which will influence the classification of the product. 4 FIRST AID MEASURES Inhalation In high concentrations may cause asphyxiation. Symptoms may include loss of mobility/consciousness. Victim may not be aware of asphyxiation. Low concentrations of CO2 cause increased respiration and headache. Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped. Skin/eye contact Immediately flush eyes thoroughly with water for at least 15 minutes. In case of frostbite spray with water for at least 15 minutes. Apply a sterile dressing. Obtain medical assistance. Ingestion Ingestion is not considered a potential route of exposure. 5 FIRE FIGHTING MEASURES Specific hazards Exposure to fire may cause containers to rupture/explode. Non flammable. Hazardous combustion products None. Suitable extinguishing media All known extinguishants can be used. Specific methods If possible, stop flow of product. Move container away or cool with water from a protected position. Special protective equipment for fire fighters In confined space use self-contained breathing apparatus. 6 ACCIDENTAL RELEASE MEASURES Personal precautions Evacuate area. Wear self-contained breathing apparatus when entering area unless atmosphere is proved to be safe. Ensure adequate air ventilation. Environmental precautions Try to stop release. Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous. Clean up methods Ventilate area. 7 HANDLING AND STORAGE Handling Suck back of water into the container must be prevented. Do not allow backfeed into the container. Use only properly specified 9451 / EDV / 21.11.2010

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Carbon Dioxide -CO2 - 2

Safety data sheet Carbon dioxide, refrigerated liquid. Creation date : Revision date : 27.01.2005 20.12.2010 Version : 2.0 equipment which is suitable for this product, its supply pressure and temperature. Contact your gas supplier if in doubt. Check regularly tightness of the plant. Refer to supplier's handling instructions. Storage Secure cylinders to prevent them falling. Keep container below 50°C in a well ventilated place. Observe "Technische Regeln Druckgase (TRG) 280 Ziffer 5" 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limit value Value type Germany - AGW value 5.000 ppm Note...

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Carbon Dioxide -CO2 - 3

Safety data sheet Carbon dioxide, refrigerated liquid. Creation date : Revision date : 27.01.2005 20.12.2010 Version : 2.0 DE / E SDS No. : 9451 page 3 / 3 9451 / EDV / 21.11.2010

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