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RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE

RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE
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RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE

Product catalog summary
Foreword
Derakane™ resins, produced by INEOS, are epoxy vinyl ester resins known for their resistance to corrosion and high temperatures, making them ideal for industrial applications. This guide provides essential data for engineers designing corrosion-resistant fiber reinforced polymer (FRP) applications.

Brief Product Description
Derakane™ resins are available in several series, each with distinct properties:
  • 411 Series: Standard epoxy vinyl ester resins, resistant to acids, alkalis, bleaches, and solvents.
  • 441-400: Low styrene monomer resins, suitable for thermal cycling.
  • 451-400: Low viscosity, unpromoted novolac epoxy vinyl ester with excellent resistance to hot water, solvents, and acids.
  • 455-400: Highly crosslinked novolac epoxy vinyl ester with a high heat distortion temperature.
  • 470 Series: Designed for exceptional thermal and chemical resistance.
  • 510A/B/C Series: Brominated resins offering fire retardance and chemical resistance.
  • 510N: Brominated epoxy novolac resin for fire retardance in hot, wet environments.
  • 515-400: Flame retardant resin with excellent thermal shock and corrosion resistance.
  • 8084: Elastomer-modified resin for high toughness and adhesion.

Chemical Resistance Table Usage
The table provides guidelines for selecting appropriate resins based on chemical exposure and temperature limits, listing chemical reagents and environments with maximum service temperatures.

Special Cases and Mixtures
Guidelines for handling mixtures and special resistance inquiries are provided, with recommendations to consult INEOS Technical Service for specific advice.

Post Cure and Veils
Post curing is recommended to extend service life, especially above 100 °C. Various veils are suggested to enhance corrosion resistance in different chemical environments.

Insufficient Information
For conditions outside the guide's scope, testing with a laminate under actual conditions is recommended to determine resin suitability.

Coatings and Linings
Coatings and linings have specific properties and may require specialist consultation for optimal application.

Introduction
This document provides guidelines for using Derakane™ epoxy vinyl ester resins in various chemical environments, emphasizing proper application techniques and post-curing processes to enhance durability and resistance.

Specifications and Procedures
Laminate linings should be applied by hand lay-up for quality reasons, with post-curing recommended to improve performance. Special precautions are necessary for environments with strongly diffusing media like HCl and HF.

Special Cases
For high gas temperatures, synthetic veils with sufficient temperature resistance are recommended. Measures should be taken to prevent sub-dewpoint conditions in environments with water vapor or acids.

Short-term Exposure/Spillage
Intermittent exposure to fumes or spills can still result in a good service life at higher temperatures than typically recommended. Consultation with INEOS Technical Service is advised for specific resin recommendations.

Chemical Resistance and Mixtures
The document highlights the difficulty in predicting the aggressiveness of chemical mixtures towards FRP and advises consulting technical resources for guidance.

Chemical Resistance Inquiry
Detailed information about the chemical nature, concentrations, service temperatures, and equipment type is required when requesting resin recommendations. A Chemical Resistance Inquiry form is provided.

Safety Precautions
Handling Derakane™ resins requires adherence to safety precautions similar to those for unsaturated polyesters. Safety Data Sheets are available for handling and disposal needs.

Notice
INEOS provides recommendations based on experience and knowledge of Derakane™ resins but does not accept legal responsibility for their use. Reproduction of the material requires permission from INEOS.

Conclusion
This guide serves as a comprehensive resource for the application and handling of Derakane™ resins, emphasizing the importance of proper procedures and safety measures.
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Catalog excerpts

RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE-1

RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE DERAKANE ™ RESINS FOR CORROSION-RESISTANT FRP APPLICATIONS

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RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE-4

DERAKANE CHEMICAL RESISTANCE GUIDE ™ FOREWORD Derakane™, Derakane™ Momentum™ and Derakane™ Signia™ epoxy vinyl ester resins (from this point forward referred to as Derakane™ resins) are designed and manufactured by INEOS. Derakane™ resins possess outstanding corrosion-resistant and temperature-resistant properties, which make them wellsuited for a variety of demanding industrial applications. With performance that has been proven over more than 50 years, Derakane™ resins not only deliver durable solutions, they also provide a high measure of confidence. This guide briefly describes the various...

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RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE-5

BRIEF PRODUCT DESCRIPTION Derakane™ 411 series resins are the globally recognized standard for epoxy vinyl ester resins. They are based on bisphenol-A epoxy resin, providing resistance to a wide range of acids, alkalis, bleaches and solvents for use in many chemical processing applications. They offer excellent toughness and fatigue resistance. Derakane™ 441-400 resins are low styrene monomer bisphenol-A epoxy vinyl ester resins with mechanical, thermal and chemical resistance properties between Derakane™ 411 and Derakane™ 470 resins. Their unique combination of high HDT and elongation makes...

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RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE-6

HOW TO USE THE CHEMICAL RESISTANCE TABLE CONTENT Each series of Derakane™ resins is based on the same epoxy (or novolac) vinyl ester resin backbone. Improvements have been made over the years for processing and stability, as seen in our recent introduction of the Derakane™ Signia™ resins. For example, Derakane™ 411-350, Derakane™ Momentum™ 411-350 and Derakane™ Signia™ 411-350 resins each are based on the same polymer backbone, and comparison studies confirm that their performance in corrosive environments is essentially equivalent. Corrosion data and case history information for each series...

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RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE-7

FOOTNOTES Information indicated in footnotes is essential in order to ensure a good service life of FRP equipment. It is strongly recommended that they are followed. 1 Double synthetic veil should be used in the CR barrier. Carbon veil can be used in alkaline environments above 50 °C/120 °F and in hydrofluoric acid environments for maximum corrosion resistance. 2 Post cure recommended to maximize service life. 3 Benzoyl Peroxide/Amine cure system recommended to increase service life. 4 Recommended, provided the recommended resin is also suitable for the solvent used for dissolution. 5 Satisfactory...

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RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE-8

POST CURE For a service temperature below 100 °C/210 °F: A post cure may extend the service life if the operating temperature is within 20 °C/40 °F of the present CR guide maximum temperature for the service. This means that a post cure can be beneficial for solvent applications with a temperature limit of 25–40 °C/80–100 °F. For a service temperature above 100 °C/210 °F: Post cure in service may be sufficient, provided the resinspecific minimum Barcol hardness values are reached before startup. VEILS For service in pure and neutral salt solutions: Post cure may, in general, not be required,...

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RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE-9

SPECIAL CASES INSUFFICIENT INFORMATION HIGH (FLUE) GAS TEMPERATURES In cases where the environment or exposure conditions are outside the scope of this guide, and thus no specific recommendations can be made, a test laminate should be exposed to the actual or simulated conditions proposed so that a final decision on resin suitability can be reached. If a synthetic veil is recommended for hot gas environments, the temperature resistance of the veil must be sufficient. COATINGS AND LININGS (REINFORCED AND NON-REINFORCED) Coatings and linings have their own specific properties and may be limited...

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RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE-10

MIXTURES OF ALTERNATING ENVIRONMENTS CHEMICAL RESISTANCE INQUIRY The information provided in this guide represents the performance of full FRP structures under continuous use in contact with the stated chemical environment (unless otherwise indicated). It is sometimes difficult to predict just how aggressive certain combinations of chemicals will be toward FRP. Some mixtures are more aggressive toward FRP than the individual components, so special attention should be paid to aggressively synergistic chemicals which cannot readily be predicted based solely on the corrosion properties of the individual...

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RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE-11

DERAKANE™ EPOXY VINYL ESTER RESINS CHEMICAL RESISTANCE INQUIRY FORM  Please e-mail this form to [email protected] or fax to +49(0)7851 99 478-30 (Europe) or your distributor. To: Technical Service Derakane™ Resins INEOS Composites E-Mail: [email protected] Comments/notes: (e.g., unusual process conditions, temperature cycling, high/ low concentrations, addition and dilution, novel design or construction, abrasion) Tel: Industry Sector/Process: (Chemical, Paper, Mining, Flue Gas …) *Equipment Type: (Tank, Scrubber, Pipe/Duct, Lining ...) Full FRP Applications or lining on steel, concrete? *Dimensions/Capacity:...

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RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE-12

CHEMICAL NAME/CAS NUMBERS CAS Number/Chemical Name 7-31-3 Methyl Formate 10-54-3 Hexane 50-0-0 Formaldehyde 50-21-5 Lactic Acid 50-70-4 Sorbitol 50-78-2 Acetylsalicylic Acid 56-23-5 Carbon Tetrachloride 56-81-5 Glycerin or Glycerol 56-93-9 Benzyltrimethylammonium Chloride 57-10-3 Palmitic Acid 57-11-4 Stearic Acid 57-13-6 Urea 57-50-1 Cane Sugar, Sugar 57-55-6 Propylene Glycol 60-24-2 Mercaptoethanol 60-29-7 Diethyl Ether 60-29-7 Ethyl Ether 60-34-4 Monomethylhydrazine 62-53-3 Aniline 62-56-6 Thiourea 62-76-0 Sodium Oxalate 64-2-8 Ethylenediaminetetraacetic acid, tetrasodium salt (EDTA) 64-17-5...

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RESIN SELECTION GUIDE FOR CHEMICAL RESISTANCE-13

CHEMICAL NAME/CAS NUMBERS (continued) CAS Number/Chemical Name 1113-38-8 Ammonium Oxalate 1191-50-0 Sodium Myristyl Sulfate 1300-21-6 Dichloroethane 1300-72-7 Sodium Xylene Sulfonate 1302-42-7 Sodium Aluminate 1303-96-4 Borax 1305-62-0 Calcium Hydroxide 1309-42-8 Magnesium Hydroxide 1310-58-3 Potassium Hydroxide 1310-65-2 Lithium Hydroxide 1310-73-2 Sodium Hydroxide 1312-76-1 Potassium Metasilicate 1313-82-2 Sodium Sulfide 1314-56-3 Phosphorous Pentoxide 1314-85-8 Phosphorus Sesquisulfide 1317-65-3 Calcium Carbonate 1319-77-3 Cresylic Acid 1327-41-9 Aluminum Chlorohydrate 1327-52-2 Arsenic Acid...

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*Prices are pre-tax. They exclude delivery charges and customs duties and do not include additional charges for installation or activation options. Prices are indicative only and may vary by country, with changes to the cost of raw materials and exchange rates.