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HETRON Resin selection guide for corrosion resistant FRP applications

HETRON Resin selection guide for corrosion resistant FRP applications
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HETRON Resin selection guide for corrosion resistant FRP applications

Product catalog summary
Foreword
Hetron™ and Derakane™ epoxy vinyl ester resins by Ashland are designed for corrosion-resistant applications in Fiber-Reinforced Plastic (FRP). This guide provides chemical resistance data for designing corrosion-resistant FRP applications, including updated information and CAS numbers. Some products have been removed; inquiries should be directed to Ashland Technical Service.
Testing and Technical Service Information
Ashland's laboratory in Dublin, Ohio, evaluates Hetron and Derakane resin laminates for corrosive service. Standard test laminate kits are available for exposure testing. Users should provide detailed chemical exposure data when requesting resin recommendations.
Resin Selection Guide
The guide categorizes resins into several series based on characteristics and applications:
  • High Performance Epoxy Vinyl Ester: Hetron 980/35 and Hetron FR998/35 for maximum heat and corrosion resistance.
  • Epoxy Vinyl Ester: Hetron 922 and Hetron FR992 for resistance to acids and bases.
  • Chlorendic Polyester: Hetron 197 Series for corrosion and heat resistance.
  • Furfuryl Alcohol Resin: Hetron 800 for resistance to organic solvents and aqueous systems.
Advantages of FRP
FRP is favored for its corrosion resistance, heat resistance, electrical and thermal insulation, and high strength-to-weight ratio. It requires low maintenance and is easy to repair.
Recommendations
Recommendations are based on field service performance, laboratory tests, and expert knowledge. Users should refer to industry standards and design guidelines for FRP equipment design.
Introduction
Hetron resins are liquid polyester and epoxy vinyl ester resins used to create fiber-reinforced structures. Developed since 1954, they are defined by ASTM and ASME standards.
Basis for Recommendations
Recommendations are based on field performance, laboratory tests, and expert knowledge. The guide is updated periodically to reflect new data, assuming ASTM C581 standard laminate construction unless noted otherwise.
FDA Applications
The FDA lists acceptable raw materials for resins. Hetron 922 and other selected resins comply with FDA regulations.
How to Use This Guide
The guide provides information on the resistance of Hetron resin-based FRP equipment under various conditions. Special considerations are needed for fumes, splash, and tank lining applications.
Epoxy Vinyl Ester Resin Composites
These resins offer enhanced mechanical properties and are suitable for high-temperature applications, resisting acids, alkalis, and solvents.
High Performance Epoxy Vinyl Ester Resin
Manufactured for maximum corrosion and temperature resistance, formulated for optimal cure with specific catalysts.
Chlorendic Polyester Resin
Suited for high-temperature and oxidizing environments, such as chimney liners and chlorine headers.
Furfuryl Alcohol Resin
Known for excellent resistance to strong alkalis and acids, not suitable for oxidizing chemicals.
Physical Properties
Typical values for mechanical properties are provided, varying from sample to sample. Barcol hardness indicates surface cure.
Mechanical Properties
Tables provide detailed mechanical properties of Hetron resins in both US and SI units, including tensile strength, modulus, and flexural strength at various temperatures.
Overview
The document is a technical guide for Hetron™ resins, focusing on mechanical, thermal, and electrical properties, as well as flame retardance. It provides specifications and recommendations for industrial applications.
Mechanical Properties
Tables detail tensile and flexural strength and modulus of Hetron resins at different temperatures, emphasizing reinforcement type and orientation.
Thermal Properties
Thermal conductivity and expansion are discussed, advising on post-curing conditions to enhance service life, especially for high operating temperatures.
Electrical Properties
Hetron resins exhibit high dielectric constants and low dissipation factors, suitable for electrical insulation applications.
Flame Retardance
Many Hetron resins are inherently flame retardant due to their halogenated chemical structure, with industry standards for flame spread ratings provided.
Recommendations
The guide recommends specific post-curing conditions and highlights the importance of reaching minimum Barcol hardness values before startup.
Concentration Chart
Provides a concentration chart converting parts per million (ppm) to percentage (%).
Baumé Concentration Chart at 25°C (77°F)
Includes a Baumé concentration chart for various acids and ammonia at 25°C.
Company Overview
Ashland Inc. is a global provider of specialty chemical products, services, and solutions, operating through five commercial units and serving customers in over 100 countries.
Legal Disclaimer
The document includes a disclaimer stating that the information provided is believed to be accurate but is not guaranteed as a warranty or representation for any particular purpose.
Contact Information
Contact details for Ashland's global headquarters and regional centers are provided.
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Catalog excerpts

HETRON Resin selection guide for corrosion resistant FRP applications-1

Hetron™ epoxy vinyl ester resins Resin selection guide for corrosion resistant FRP applications

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HETRON Resin selection guide for corrosion resistant FRP applications-2

English Foreword 2 Testing and Technical Service Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Chemical Resistance Inquiry Form 5 How to Use This Guide 6 Physical Properties 7 Postcuring the Laminate . 10 Electrical Properties 12 Flame Retardance 12 Chemical Names / CAS Numbers 52 Resin Selection Guide 54 Spanish Prólogo . 13 Información de Ensayos y de Servicio Técnico 15 Solicitud de Informatión Sobre Resistencia Química . . . . . . . . . . . . . . . . . . . . . . . . . .16 Como Usar Esta Guía 17 Propiedades Físicas . . . . . . . . . . . . . . . . . . ....

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HETRON Resin selection guide for corrosion resistant FRP applications-3

French Avant-propos 25 Informations concernant les essais et le service technique . 27 Demande de résistance chimique . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .28 Comment utiliser ce guide? 29 Propriétés physiques 31 Post-cuisson d’un stratifié . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .31 Propriétés électriques 36 Tenue à la flamme 36 Noms chimiques en Anglais, Numéros CAS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .50 Guide de sélection de résine . 52 Portuguese Prefácio...

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HETRON Resin selection guide for corrosion resistant FRP applications-4

Foreward Hetron™ and Derakane™ epoxy vinyl ester resins are designed and manufactured by Ashland. These resins possess outstanding corrosion-resistant properties and satisfy critical requirements in Fiber- Reinforced Plastic (FRP). Because of their outstanding corrosion-resistant properties, Hetron and Derakane resins are particularly well suited for demanding industrial applications. This latest edition of the Hetron Resin Selection Guide describes the various Hetron resins, and presents detailed chemical resistance data engineers need for specifying and designing corrosion-resistant FRP applications....

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HETRON Resin selection guide for corrosion resistant FRP applications-5

We have a Hetron™ Resin for your FRP Equipment Needs. Resin Series Characteristics Suggested Applications HIGH PERFORMANCE EPOXY VINYL ESTER Hetron 980/35 High performance epoxy vinyl ester resin formulated to provide maximum heat and corrosion resistance to strong oxidizing chemicals. Equipment requiring maximum corrosion resistance to pulp and paper bleaching chemicals. Hetron FR998/35 Flame retardant epoxy vinyl ester resin. Class I (ASTM E84) without antimony additives. Improved resistance to hydrocarbon solvents and oxidizing media. Superior thermal properties. Equipment requiring superior...

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HETRON Resin selection guide for corrosion resistant FRP applications-6

ADVANTAGES Fiberglass reinforced plastic (FRP) has been used for various types of equipment in the chemical processing industry since the early 1950s. Its use has continued to grow in pulp and paper, power, waste treatment, semi-conductor, mineral processing, petrochemical, pharmaceutical, and other industries. Process vessels of all shapes and sizes, scrubbers, hoods, ducts, fans, stack liners, pipes, pumps, pump bases, misteliminator blades, grating, and tank lining systems are just a few examples of products made of FRP. The chief reason for the popularity of these materials is their excellent...

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Hetron™ Resins CHEMICAL RESISTANCE INQUIRY FORM Date: Number of page: To: Technical Service Hetron resins Ashland Performance Materials From: Name: Company: E-Mail: [email protected] E-Mail: Fax: +1.614.790.6157 Fax: Tel: Project name: End-user: Engineering: Fabricator: Industry Sector/Process: (Chemical, Paper, Mining, Flue Gas…) Equipment Type: (Tank, Scrubber, Pipe / Duct, Lining... ) Tank or Pipe? Other: Full FRP Applications or lining on steel, concrete? Dimensions/capacity: (Height, Diameter, Flow Rate…) Operating Conditions Concentration / Units (g/L, oz/gal, %) Chemical environment or...

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HETRON Resin selection guide for corrosion resistant FRP applications-8

INTRODUCTION Liquid polyester and epoxy vinyl ester resins, as purchased from the resin supplier, are actually polymers dissolved in styrene monomer. The fabricator cures these resins to a solid state, reacting the polymer together with the styrene in the presence of glass reinforcements to produce a fiber reinforced rigid structure. The standards for these structures are defined by organizations such as ASTM and ASME. The development and manufacture of Hetron, epoxy vinyl ester resins has been a continuing process since 1954. They have been used to fabricate thousands of different types of corrosion...

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HETRON Resin selection guide for corrosion resistant FRP applications-9

HIGH PERFORMANCE EPOXY VINYL ESTER RESIN Manufactured under a patented process, these resins offer maximum corrosion and temperature resistance to acids, alkalis, hypochlorites, and many solvents. These products have been formulated for maximum performance with methyl ethyl ketone peroxides. It is well documented that these catalysts provide optimal cure and thus maximum corrosion resistance. Hetron 980/35: A novolac epoxy vinyl ester resin formulated with less than 35% styrene. Provides maximum heat and corrosion resistance to strong oxidizing chemicals. Hetron FR998/35: Highly flame retardant...

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POSTCURING THE LAMINATE For a service temperature below 100ºC (212ºF): A postcure may extend the service life if the operating temperature is within 20ºC (40ºF) of the present CR guide maximum temperature for the service. This means that a postcure can be beneficial for solvent applications with a temperature limit of 25º-40ºC (80º-100ºF). For service temperature above 100ºC (212ºF): Postcure in service may be sufficient, provided the resin specific minimum Bardol hardness values are reached before start up. For service in pure and neutral salt solutions: Postcure may, in general, not be required,...

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11 Hetron™ Resin Selection Guide English TABLE 3 (SI units) COMPOSITE PROPERTIES VERSUS GLASS CONTENT (TYPICAL VALUES) Resin M/M M/Wr/M/Wr/M Glass content % 25 40 Hetron FR998/35 Tensile Strength, MPa 83 162 Tensile Modulus, MPa 7998 12204 Flexural Strength, MPa 145 358 Flexural Modulus, MPa 5447 10687 Hetron 980/35 Tensile Strength, MPa 58 179 Tensile Modulus, MPa 6688 13238 Flexural Strength, MPa 113 378 Flexural Modulus, MPa 5585 10480 Hetron 922 Tensile Strength, MPa 91 125 Tensile Modulus, MPa 5929 10825 Flexural Strength, MPa 185 258 Flexural Modulus, MPa 6826 10411 Hetron FR992 Tensile...

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*Prices are pre-tax. They exclude delivery charges and customs duties and do not include additional charges for installation or activation options. Prices are indicative only and may vary by country, with changes to the cost of raw materials and exchange rates.