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HETRON and AROPOL Fabricating guide

HETRON and AROPOL Fabricating guide
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HETRON and AROPOL Fabricating guide

Product catalog summary
Product Description
The document is a comprehensive guide on fabricating composites using HETRON® and AROPOL™ resins, known for their corrosion resistance and flame retardance. These resins are suitable for various fabrication methods such as hand lay-up, spray-up, and filament winding. A detailed table lists different resin types, their applications, and properties.
Catalysts, Promoters, and Inhibitors
This section discusses the role of catalysts like Methyl Ethyl Ketone Peroxide (MEKP) and Benzoyl Peroxide (BPO) in resin curing. It emphasizes adjusting catalyst and promoter levels to control gel time and ensure proper curing. Inhibitors can extend gel time if necessary.
Additives
Various additives are discussed, including thixotropes for viscosity control, antimony oxides for flame retardance, and other fillers for enhancing specific properties of the composites.
Reinforcements
The document outlines different reinforcement materials like chopped strand mat and woven roving, which enhance the mechanical properties of the composites.
Resin Preparation
Guidelines for preparing resins, including adjusting promoter/catalyst levels and making test laminates, are provided. Post-curing processes are discussed to ensure optimal performance.
Fabrication Methods
Various fabrication techniques such as hand lay-up, spray-up, and filament winding are detailed, along with standards and best practices for each method.
Inspection and Quality Control
Inspection methods like visual inspection and Barcol hardness testing are described to ensure the quality of the finished laminate.
Health, Safety, and Regulatory Information
This section covers safety data, handling of styrene, flammability concerns, and proper storage and disposal of resins.
Appendices
The appendices provide additional resources such as promoter and catalyst addition tables, technical service contacts, and troubleshooting guides for curing resins.
Exotherm Control and Inhibitors
Copper naphthenate is used to control exotherm in resin formulations. Inhibitors like TBC, HQ, and THQ are used to extend gel times, especially in high-temperature conditions.
Safety and Handling
Promoters must be mixed thoroughly into the resin before adding catalysts to prevent explosions. Safety data sheets should be consulted for all chemicals used.
Thixotropes and Flame Retardants
Thixotropes like fumed silica are used to thicken resins. Antimony oxides enhance flame retardancy in halogenated resins, while alumina trihydrate is used for both halogenated and non-halogenated systems.
Fillers and Additives
Calcium carbonate and kaolin clays are used as fillers to increase stiffness and reduce costs, but are not recommended for corrosion-resistant applications.
Reinforcement and Laminate Construction
The standard reinforcement sequence involves a resin-rich layer followed by chopped strand mat and woven roving. Different types of fiberglass reinforcements are used depending on the application.
Veil Materials
Various veil materials used in the corrosion industry are discussed, including synthetic, carbon, and glass veils.
FDA Compliance
Certain HETRON and AROPOL resins comply with FDA regulations for food contact.
Fabrication Processes
  • Hand Lay-Up: A manual process suitable for low-volume production.
  • Spray-Up: A faster method using a chopper gun to apply resin and fiberglass.
  • Filament Winding: Ideal for round equipment, producing uniform structures.
  • Pultrusion: A continuous process for creating parts with constant cross-sections.
  • Centrifugal Casting: Used for fabricating cylinders.
  • Resin Transfer Molding (RTM): A closed mold process suitable for medium volume production.
Inspection and Quality Control
  • Visual Inspection: Detects imperfections such as air bubbles and cracks.
  • Barcol Hardness Test: Measures the degree of cure.
  • Acetone Sensitivity Test: Assesses cure extent.
Finishing Processes
Methods include applying a resin topcoat with wax and gel-coating or painting for color and weather protection.
Safety and Handling
Material Safety Data Sheets (MSDS) provide health and safety information for handling HETRON and AROPOL resins.
Flammability
HETRON and AROPOL liquid resins are flammable due to the presence of styrene or other monomers.
Health Concerns
  • Skin Contact: Wear protective gloves and clothing.
  • Eye Contact: Use eye protection.
  • Inhalation: Minimize inhalation of styrene vapors.
  • Ingestion: Swallowing resins is harmful.
  • Chronic Health Effects: Styrene is classified as possibly carcinogenic.
Resin Spills
Small spills can be wiped up. Larger spills require absorbent materials and proper disposal.
Storage
Store resin drums below 80°F (27°C) away from heat.
Disposal
Follow regulations for hazardous material disposal.
Tables
The document includes tables detailing typical gel times for various HETRON resins under different conditions.
Introduction
The document provides technical guidance on addressing issues related to laminate curing and surface quality.
Specifications and Procedures
Outlines potential issues such as uneven curing and tacky surfaces.
Recommendations
For wrinkle issues, the document suggests using specific mat weights and reducing resin viscosity.
Quality and Safety Standards
Ashland Specialty Chemical Company emphasizes its commitment to safety and environmental responsibility.
Contact Information
Provides contact details for technical and customer service support.
Disclaimer
Includes a disclaimer regarding the accuracy of the information.
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Catalog excerpts

HETRON and AROPOL Fabricating guide-1

A Guide ToFabricating Composites With HETRON > TM andAROPOL > Now With FCAT Data! Resins > Ashland Specialty Chemical Company is the leading supplier of resins for corrosion resistant and flame retardant composites Next size="-3">

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HETRON and AROPOL Fabricating guide-2

Previous |Contents |Next > Product Description Fabrication Methods Fabrication Standards . . . . . . . . . . . . . . . . . . . .24 Hand Lay-Up . . . . . . . . . . . . . . . . . . . . . . . . . . . .26 Spray-Up . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .27 Filament Winding . . . . . . . . . . . . . . . . . . . . . . .28 Pultrusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .28 Centrifugal Casting . . . . . . . . . . . . . . . . . . . . . .29 Resin Transfer Molding . . . . . . . . . . . . . . . . . . .29 Linings . . . . . . . . . . . . . . . . . . . . . . ....

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HETRON and AROPOL Fabricating guide-3

Previous |Contents |NextSECTION 1 > 3 Previous |Contents |Next >

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HETRON and AROPOL Fabricating guide-6

Previous |Contents |Next 1 There are two primary types of catalysts recommended for curing HETRON andAROPOL resins at room temperature:methyl ethyl ketone peroxide (MEKP) and benzoyl peroxide (BPO).A third,less common,catalyst type is cumene hydroperoxide (CHP) which is often recommended for blending with MEKP.In other processes,such as pultru- sion,different types of catalysts are used.Catalysts for the pultrusion process are heat activated and are not used with promoters.The proper choice of a catalyst is critical to achieving expected chemical resistance.Caremust be taken not to select catalysts...

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HETRON and AROPOL Fabricating guide-7

T-butyl Peroxybenzoate TBPB is a secondary catalyst that can be used in addition to MEKP,BPO,or CHP.The addition of TBPB assists in achieving a higher degree of cure.We recommend TBPB at 0.2%,based on resin.The addition of TBPB to resin will shorten the pot life.Please consult Ashland Technical Service for more information on TBPB. > Previous |Contents |Next form and the crystals in 98% active form.To achieve the same gel time with paste andcrystals,half the amount of crystals should be used as paste.For example,2.0 grams of paste will react to give the same gel time as 1.0 gram of the crystals.BPO...

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HETRON and AROPOL Fabricating guide-8

Copper Naphthenate Copper naphthenate is available as a green paste that typically contains 6 - 8% elemen- tal copper.It is included in a formulation to control the exotherm of blends intended for MEKP catalyzation.If low hydrogen peroxide containing MEKPs are used,the impact on the peak exotherm is marginal.However,if standard MEKPs are used,copper naphthen- ate will lower the exotherm and lengthen the time from gel to peak,without effecting the gel time.Typical levels of copper recommended for exotherm control are 0 400 ppm.Copper naphthenate should be added to the formulation the same day...

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HETRON and AROPOL Fabricating guide-9

Previous |Contents |Next TBC,HQ,and THQ can be used with MEKP,BPO,and CHP catalyst systems.However,careshould be taken not to add too much inhibitor,which could result in permanent under- cure,low Barcol,or reduced corrosion resistance.Recommended inhibitor levels vary from inhibitor to inhibitor and from resin to resin.A general guide for addition levels is up to 0.30% of a 10% solution,however,Ashland Technical Service should be contacted for instructions on adding inhibitors to specific resin systems.Special attention to additives is necessary when fabricating for FDA applications.Title 21CFR...

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HETRON and AROPOL Fabricating guide-10

Previous |Contents |Next SECTION 3 > HETRON FR 9923% Sb HETRON FR 9923% NYACOLHETRON FR 992 2 O 3 Laminates containing antimony trioxide,antimony pentoxide,and no antimony oxide.. > 10 Previous |Contents |Next >

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HETRON and AROPOL Fabricating guide-12

Air Release Agents Wax Topcoats Air release agents can be added to the resin (0.05-0.5%) to decrease foaming.Excessive levels of air release agents can cause a laminate to be cloudy,therefore recommended levels should not be exceeded.Contact Ashland Technical Service for additional information. Some resins are subject to surface inhibition when cured in the presence of air.Air inhibition affects the cure and corrosion resistance of the outermost resin layer,which results in an acetone sensitive,potentially tacky surface.A wax-containing topcoat approximately 2.0-3.5 mil (51-89 m) thick applied...

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HETRON and AROPOL Fabricating guide-13

Previous |Contents |Next The wax/styrene solution is made by dissolving 20 g of a fully refined paraffin wax(melting point = 130-140F (54-60аC)) in 180 g of warm styrene (110F (43аC)).The solu- tion is then added at the rate of 2% to the resin and mixed thoroughly.The resin solu- tion should then be promoted and catalyzed as normal.Predissolved wax solutions are also available from FRP distributors. Abrasion Resistant Additives An abrasion resistant corrosion liner is necessary when operating conditions involve slurries or other applications with abrasive particles that can abrade the corrosion...

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HETRON and AROPOL Fabricating guide-15

Previous |Contents |Next structural portion of the laminate can also be filament wound where this layer typicallyhas a minimum of 60% glass.The thickness of this layer will vary depending on the equipment being fabricated.A final wax topcoat or gelcoat is then applied to the exteri- or of the equipment to prevent air inhibition. Types of Reinforcements The following discussion provides general guidelines for fiberglass selection,however, the glass manufacturer should be contacted for specific recommendations.Regardless of glass type,each should be thoroughly evaluated in a test laminate before...

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HETRON and AROPOL Fabricating guide-16

Chopped Strand Mat Two primary types of chopped strand mat are used in the corrosion industry,EӔand ECRӔglass.Chopped strand fibers are generally > Previous |Contents |Next CӔ-glass veil is typically recommended for most corrosion environments.However,synthetic veil is preferred in some environments such as those con- taining fluoride compounds.Synthetic veil is pre- ferred in other environments,which are noted in the resin selection guide.When using synthetic veil with less flexible resins such as chlorendic polyesters,a non-apertured synthetic veil type is recommended to minimize stress in...

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HETRON and AROPOL Fabricating guide-17

Continuous Strand Roving > Previous |Contents |Next Most continuous strand roving comes as unwoven strands of glass wound into a cylindrical package for additional processing.Continuous strand roving is used in filament winding and pul- trusion or can be chopped into fibers for spray-up applications to replace chopped strand mat. Woven Roving Woven roving consists of continuous glass fiber rovings that are woven together to form a heavy mat which is available in a variety of thicknesses and weights.Alternating layers of woven roving and chopped strand mat are used in the structural portion of...

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*Prices are pre-tax. They exclude delivery charges and customs duties and do not include additional charges for installation or activation options. Prices are indicative only and may vary by country, with changes to the cost of raw materials and exchange rates.