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DERAKANE Fabricating Tips

DERAKANE Fabricating Tips
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DERAKANE Fabricating Tips

Product catalog summary
Foreword
This document offers guidance for fabricators using DERAKANE and DERAKANE MOMENTUM™ epoxy vinyl ester resins in fiber reinforced plastic (FRP) applications, highlighting their chemical resistance, heat performance, and toughness. It stresses the importance of selecting appropriate materials and adhering to safe practices.
Section 1: Selecting Reinforcements, Initiators, and Cure-control Additives
Details the selection of materials for corrosion-resistant structures, including seven types of reinforcements like surfacing veil and woven roving, emphasizing high-quality materials and trained personnel.
Section 2: Other Additives
Covers additives such as surfactants and antifoam agents that enhance resin properties.
Section 3: Food Contact and FDA/USDA Compliance
Provides guidelines for using resins in food contact applications and ensuring compliance with FDA/USDA standards.
Section 4: Formulating Guide
Includes instructions for preparing resin masterbatches and measuring small chemical quantities.
Section 5: Gel Time Formulations
Offers formulations to control resin gel time, crucial for processing.
Section 6: Working Life of Resins
Discusses factors affecting resin working life, including antimony compounds.
Section 7: Troubleshooting Guide
Addresses common issues like slow gelling and resin not hardening, providing solutions.
Section 8: Fabricating Tips
Provides tips for making laminates and applying FRP linings, including postcuring techniques.
Section 9: Inspecting a Laminate
Guidelines for checking cure completeness and recognizing defects in FRP laminates.
Section 10: Other Processing Techniques
Describes techniques like spray-up applications and filament winding.
Section 11: Industrial Health Information
Details safety data, fire hazards, and first aid measures for safe material handling.
Section 12: Resin Storage
Provides recommendations for storing resins, including temperature guidelines and shelf life considerations.
Introduction
Offers technical information on using DERAKANE resins in composite polymer applications, focusing on materials and processes for high-quality laminates.
Specifications and Materials
Discusses the use of glass fibers in hand lay-up processes and the importance of compatible sizing finishes for applications like filament winding.
Storage Recommendations
Emphasizes storing glass fiber products in a clean, dry environment to prevent contamination.
Initiators, Promoters, Accelerators, and Retarders
Details chemical components used in curing DERAKANE resins, emphasizing correct ratios and thorough mixing.
Safety Considerations
Advises on handling chemicals with protective clothing and avoiding direct mixing of promoters with peroxide catalysts.
Gel Time and Temperature
Provides tables illustrating gel time adjustments by varying initiators and promoters.
Trade Names and Suppliers
Lists trade names and suppliers for various materials.
Surfactants and Antifoam Agents
Outlines best practices for minimizing air bubbles in laminates.
Conclusion
Serves as a guide for professionals working with DERAKANE resins, providing essential information on materials, processes, and safety measures.
Specifications and Compliance
Discusses FDA compliance for agents like Foamkill 8G and the use of thixotropic additives to control resin flow.
Mold Release Agents
Describes agents like wax and PVA for facilitating part removal from molds.
Ultraviolet Protection
Recommends UV absorbers and pigments to prevent surface chalking.
Air Inhibition and Wax Topcoats
Discusses using wax/resin topcoats to prevent air inhibition.
Food Contact Compliance
Details compliance requirements for DERAKANE resins in food contact applications.
Masterbatch Preparation
Emphasizes consistent curing characteristics through proper mixing.
Safety Precautions
Highlights necessary safety measures and waste disposal compliance.
Specifications and Procedures
Provides instructions on preparing and using DERAKANE resins, emphasizing accurate measurement of components.
Gel Time Formulations
Illustrates the relationship between temperature and gel times for different resins.
Factors Affecting Resin Working Life
Outlines conditions affecting resin working time and adjustments for shop conditions.
Effect of Antimony Compounds
Advises on the impact of antimony compounds on gel times.
Troubleshooting Guide
Offers solutions for common issues with ambient temperature cure resins.
Making a Laminate
Includes a step-by-step guide for making FRP laminates, emphasizing safety and preparation.
Safety and Preparation
Advises on safety measures and preparation of mold surfaces.
Laminate Construction
Details a typical laminate construction sequence and expected physical properties.
Mixing and Measuring Resin
Outlines the process for measuring and mixing resin for desired pot life.
Preparation and Application of DERAKANE Resin
Provides steps for measuring, mixing, and applying DERAKANE resin.
Conductive Lining System
Describes using graphite and carbon veil for grounding static charges in FRP vessels.
Postcure Recommendations
Recommends postcure conditions to extend service life.
Secondary Bonding
Emphasizes proper surface preparation for secondary bonding.
Test Patch Application
Recommends applying a test patch to ensure surface readiness.
Lining Procedures
Provides steps for lining various surfaces, emphasizing preparation and inspection.
Safety and Maintenance
Emphasizes safety, planning, and maintaining a clean work area.
Abrasion Considerations
Discusses mitigating abrasion effects on FRP surfaces.
Specifications and Materials
Discusses materials for abrasion resistance and provides data on wear resistance.
Inspection and Testing Procedures
Outlines procedures for checking cure completeness and recognizing defects in FRP laminates.
Fabrication Techniques
Describes various fabrication techniques for FRP, emphasizing resin viscosity and reinforcement materials.
Recommendations and Best Practices
Provides recommendations for ensuring quality in FRP production.
Composite Polymers Overview
Discusses reinforcement, die temperature settings, and resin transfer molding (RTM) techniques.
Mold Releases and Equipment
Describes mold releases and equipment used in RTM.
Industrial Health Information
Provides safety guidelines for handling DERAKANE resins.
Physical Properties and Safety
Lists physical properties of DERAKANE resins and addresses safety concerns.
Reactivity and First Aid
Details first aid measures and the importance of protective equipment.
Personnel Protection
Emphasizes minimizing contact with resins and ensuring proper ventilation.
Handling and Safety
Discusses handling precautions for DERAKANE resins.
Spill Management
Provides guidelines for managing small and large spills.
Environmental and Disposal Information
Emphasizes compliance with regulations for disposal and storage.
Storage Guidelines
Recommends storage conditions to prevent premature polymerization.
Resin Shelf Life
Discusses shelf life variations and aeration for extending shelf life.
Bulk Storage Recommendations
Provides recommendations for bulk storage systems to maintain resin quality.
Product Stewardship
Emphasizes reviewing product applications for health and environmental impacts.
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Catalog excerpts

DERAKANE Fabricating Tips-2

Selecting reinforcements, initiators and cure-control additives . . . . . . . . . . . . . . . . . . . .3 Reinforcement types . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3Glass storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4Initiators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4Non-foaming MEKP substitutes . . . . . . . . . . . . . . . . . . . . . . . ....

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DERAKANE Fabricating Tips-3

Making a laminate and applying FRP linings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22 Making a test laminate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22Guide to making a laminate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .24Guide to making a conductive lining . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26 Postcuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ....

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DERAKANE Fabricating Tips-4

This bulletin is intended to provide practical information that will help fabricators choose themost effective combination of DERAKANEand DERAKANEMOMENTUM > epoxy vinylester resins and reinforcement for many end-use applications.Excellent chemical and corrosion resistance coupled with outstanding heat performance andtoughness have made DERAKANEresins the material of choice for a wide range of fiber reinforced plastic (FRP) applications. All conventional fabricating techniques are used with DERAKANEresins to produce FRP structures having an advantageous combination of strength, toughness and corrosion...

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DERAKANE Fabricating Tips-5

Nexus > Ү veil (Dacron > 1 homopolymer) > Chopped strand CӔ glass > 1 E. I. DuPont de Nemours & Co.

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DERAKANE Fabricating Tips-6

Two mats are generally used with the surfacing veil to form the corrosion liner, providingabout 80 mils of additional corrosion protection. Chopped strand mats also are used in the structural layer between layers of woven roving or as the sole reinforcement for the structural wall.The chopped mat layers in the finished laminate consist of about 70% resin and 30%glass. The short fiber bundles and high resin content help to produce laminates with good strength and excellent chemical resistance.Saint-Gobain Vetrotex > 2 M113 and OC > 2 723A and MPM > 3 mats have given consistently good results with...

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DERAKANE Fabricating Tips-7

Smaller amounts of initiators and accelerators are required for curing DERAKANEresins thanfor curing polyesters because of the efficient molecular structure of DERAKANEresins. As already stated, it is essential to use the correct ratios of the activators. Also, thorough mixing is necessary for optimum results, and it is important to mix the activators into the resin in the proper sequence. NOTE: The promoter should never be mixed directly with a peroxide catalyst (such as MEKP).Mixing would cause a violent reaction, and a fire or explosion could result. For example, standard procedure is to mix...

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DERAKANE Fabricating Tips-8

Since BPO powders and pastes tend to settle to the bottom of resin solutions, ensure that thestirrer used evenly disperses BPO throughout the resin. For optimum results, the ratio should be from 10 to 20 parts (preferably 10 to 15 parts) active BPO to one part dimethylaniline. Ratios outside that range may cause resin not to gel. The resin may gel and not cure, or a high degree of resin cure may never develop, even with post-curing.Diethylaniline is a less active accelerator than dimethylaniline and can be used when longer geltimes are required. Optimum ratios are from 4 to 12 parts active BPO...

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DERAKANE Fabricating Tips-12

Air bubbles in a laminate reduce its strength and may seriously affect its corrosion resistance properties. Air bubbles in the corrosion liner > 1 can be more damaging than those in the structurallayer. The following practices should always be followed to minimize air bubbles:1.Avoid violent mixing which mixes air into resin. However, be sure the catalyst is mixed thoroughly into the resin.2.Apply resin to the mandrels first, then apply glass, and roll it into the resin. Air bubble problems are inevitable when resin is applied to dryӔ glass.3.Roll the laminate from the center to the edges. Roll...

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DERAKANE Fabricating Tips-14

Wax, or films of PVA, Mylar > 1 , or cellophane may be used as mold release agents to facilitate the removal of fabricated parts from metal, wooden, cardboard or plastic molds and mandrels. It is important to check the release characteristics of any mold release agent before using it in production. > Wax Hard-based paraffin waxes and carnauba waxes are used successfully as mold release agents in part fabrication with DERAKANEresins. Several brands provide excellent results, including:Meguiars > 2 Mirror GlazeՕTrewax > 3 JohnsonՒs > 4 Traffic WaxTR > 5 Mold ReleaseThese products are generally...

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DERAKANE Fabricating Tips-15

FRP parts fabricated with either polyester or vinyl ester resins may display surface chalking and discoloration after long exposure to ultraviolet radiation. These effects may be reduced or eliminated by: incorporating UV absorbers into the resinՕ pigmenting outer resin layers painting the surface with epoxy-polyamide paints Օ incorporating fillersUV absorbers do not always provide effective protection for long-term service and they alsoinhibit resin cure. Two that can be used without inhibiting the resin are: Cyasorb > 6 UV-24Օ Tinuvin > 7 326These products are incorporated into the external...

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DERAKANE Fabricating Tips-17

DERAKANE411, 411C and 441-400 epoxy vinyl ester resins, when properly formulated andcured, will comply with the U.S. Food, Drug and Cosmetic Act, as amended, and applicable FDA regulations (21 CFR 177.2420). These resins may be used as articles or components of articles intended for repeated use in contact with food, subject to certain limitations described in that regulation. NOTE: It is the responsibility of the customer/user to test the finished laminate or coating to determinecompliance with 21 CFR 177.2420 and all other appropriate regulations. DERAKANE411, 411C and 441-400 epoxy vinyl ester...

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*Prices are pre-tax. They exclude delivery charges and customs duties and do not include additional charges for installation or activation options. Prices are indicative only and may vary by country, with changes to the cost of raw materials and exchange rates.