Polyurethanes Product Line
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ACE brochure rev. April 2013_v 6/4/13 9:17 AM Page 1 Adhesives, Coatings and Elastomers Polyurethanes Product Line

ACE brochure rev. April 2013_v 6/4/13 9:18 AM Page 2 RUBINATE® and SUPRASEC® MdI Specialty Isocyanates Comprehensive Technical Support and Applications Development 3 Modified Monomeric Alternatives 4 Polyurea Prepolymers 6 Primers, Sealers and MDI Isocyanate Crosslinkers When it comes to polyurethane chemistry for the Adhesives, 8 Moisture Cure Prepolymers is your most important resource. Our experience can help you at Coatings & Elastomers (ACE) marketplace, Huntsman Polyurethanes virtually every stage of product development, from formulation assistance to manufacturing. 10 Specialty MDI...

ACE brochure rev. April 2013_v 6/4/13 9:18 AM Page 3 Huntsman Polyurethanes is among the industry leaders in chemistry, technology and the manufacture of products for the Adhesives, Coatings and Elastomers (ACE) market. Equivalent Weight StAndArd PolymEriC SUPRASEC 5025 Isocyanate Low acidity polymeric optimal for controlled system reactivity RUBINATE M Isocyanate Standard polymeric MDI modifiEd PolymEriC RUBINATE 9016 Isocyanate Slow-reacting polymeric to provide extended open times RUBINATE 1820 Isocyanate Medium functionality modified polymeric SUPRASEC 9615 Isocyanate Polymeric MDI...

ACE brochure rev. April 2013_v 6/4/13 9:18 AM Page 4 Monomeric MDI Pure 4,4' methyl diphenyl diisocyanate (4,4' MDI) is the material of choice in urethane applications requiring high dynamic elastomeric properties. Although 4,4' MDI has a relatively high melting point and is solid at room temperature, Huntsman Polyurethanes has developed a family of specialty MDI isocyanates that can provide a portion of the benefits of 4,4' MDI, but are liquid at room temperature. Equivalent Weight StAndArd PurE RUBINATE 44 Isocyanate Pure 4,4' MDI melting point 38°C modifiEd monomEriC mixEd...

ACE brochure rev. April 2013_v 6/4/13 9:18 AM Page 5 Modified Monomeric Alternatives The photos above represent typical color. Actual color may vary slightly from lot to lot. SUPRASEC 9561 Isocyanate • Specifically designed to provide significant improvements in shelf life and cold storage stability • Used extensively in RIM elastomers and as a precursor for 1k prepolymers RUBINATE 44 Isocyanate • > 98% 4,4' MDI • Solid at room temperature • 38˚C Melting Point RUBINATE 9433 Isocyanate • Low functionality liquid pure • Also contains some 2,4' isomer • Used as a precursor for 1k prepolymers...

ACE brochure rev. April 2013_v 6/4/13 9:18 AM Page 6 Polyurea Prepolymers The concept of polyurea spray elastomer technology was introduced about 25 years ago. This application was based on the reaction of an isocyanate component with an amine blend to produce a polyurea elastomer system. Equivalent Weight RUBINATE 9447 Isocyanate • Contains propylene carbonate. • Designed for Shore A 80-90 hardness polyurea coatings. RUBINATE 9495 Isocyanate • Contains propylene carbonate. • Designed for Shore D 40-50 hardness polyurea coatings. RUBINATE 9009 Isocyanate • Designed for Shore D 40-50...

ACE brochure rev. April 2013_v 6/4/13 9:18 AM Page 7 urEtHAnE link The difference lies in the Resin urEA link What’s the difference between Polyurea and Polyurethane? PolyurEA • The majority are spray-applied with an equal volume ratio • Fast cure – tack free in seconds - No catalysts required - Lower reaction activation energy • Broader temperature application range, mainly lower temperatures • Very good physical properties - Chemical resistance - Better temperature stability - Lower sensitivity to moisture • Contains no OH groups in the resin • Spray-applied, but can be at a number of...

ACE brochure rev. April 2013_v 6/4/13 9:18 AM Page 8 Primers, Sealers and MDI Isocyanate Crosslinkers % NCO Equivalent Weight SUPRASEC 9611 Isocyanate • A novel one-component (1k), VOC-exempt approach to polyurethane primers. • Can be used as is or modified with catalysts, pigments or other additives. SUPRASEC 9584 Isocyanate • Designed for usage in two-component primer systems (2k), this VOC-exempt PrimEr & SEAlErS product works well with green resins, such as castor oil, to produce a primer on porous substrates. RUBINATE 9259 Isocyanate • A chemically-modified MDI that can readily form an...

ACE brochure rev. April 2013_v 6/4/13 9:18 AM Page 9 StAbility of 50:50 mixturES of mdi iSoCyAnAtE & wAtEr 5 MINUTES Crosslinking/catalyzing technology for latex or acrylic emulsions Typical emulsion adhesive formulation To address the need for improved water-based coatings and adhesives, higher functionality isocyanates, specially modified to be readily dispersible in water-based polymer dispersions/emulsions, have been developed. Calcium Carbonate Polyvinyl Alcohol This technology allows for the use of an MDI isocyanate as a crosslinker for adhesives and coatings emulsions based upon...

ACE brochure rev. April 2013_v 6/4/13 9:18 AM Page 10 Moisture Cure Prepolymers % NCO Equivalent Weight moiSturE CurE PrEPolymErS RUBINATE 9272 Isocyanate High elongation prepolymer, can be used as a flexibilizer for RUBINATE 9511 or RUBINATE 9234 RUBINATE 9040 Isocyanate Clear, slow curing, flexible binder ideal for rubber crumb applications SUPRASEC 9577 Isocyanate Fast curing, amber prepolymer with improved heat and moisture resistance RUBINATE 9511 Isocyanate Amber prepolymer that provides excellent tensile, tear strength and bonding characteristics RUBINATE 9234 Isocyanate Comparable...

ACE brochure rev. April 2013_v 6/4/13 9:18 AM Page 11 Polymer Concrete The next generation of trowelable flooring combine urethane resin binders with Portland cement and graded aggregates to deliver superior qualities for application in manufacturing areas, food processing facilities, cold storage and parking decks. These systems, based upon RUBINATE and SUPRASEC MDI Isocyanate technology from Huntsman Polyurethanes are heavyduty, trowel applied urethane-modified cementitious toppings. In addition to excellent chemical resistance, these systems are moisture vapor tolerant or “breathing” and...