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Time-resolved absorption spectrum analysis system

Time-resolved absorption spectrum analysis system

Time-resolved absorption spectrum analysis system

Product catalog summary
Overview
The document outlines the T-Absorption A8005 system, designed for time-resolved absorption spectrum analysis. It measures transient absorption spectra in short timeframes, analyzing reactive intermediates in photoreactions across various mediums such as solutions, solids, and membranes.
Key Features
  • High time resolution and dynamic range with a high signal-to-noise ratio.
  • Simultaneous multi-wavelength measurements using a single shot.
  • Automated measurements controlled by computer systems.
System Configuration
The system comprises a streak camera, spectrograph, digital delay generator, and optical components. It uses a high dynamic range streak camera (C13410-01A) and a digital CMOS camera (ORCA®-Flash4.0 V3) for detection and imaging.
Functions and Performance
  • Temporal resolution: Less than 7 ns with a nanosecond Q-SW YAG laser.
  • Measurement time range: 20 ns to 1 ms.
  • Measurement wavelength range: 250 nm to 750 nm.
  • Measurement OD value: 0.005 for single shot, 0.02 or less.
Operating Principle
The streak camera converts incident light into electrons, which are swept across a phosphor screen to create a streak image. This image is read by a digital camera, allowing for the measurement of temporal variations in light intensity.
Specifications
  • Streak camera: Temporal resolution better than 5 ps, spectral response from 200 nm to 850 nm.
  • Spectrograph: Focal distance of 300 mm, variable slit width, and high light condensing efficiency.
  • Digital delay generator: 4 output channels, delay resolution of 5 ps.
Measurement Examples
Examples include time-resolved transient absorption spectral streak images of singlet-singlet and triplet-triplet absorption in various substances, showcasing the system's capability to capture detailed spectral data.
Applications
The system is suitable for analyzing nonfluorescent and fluorescent samples, with specific functions for measuring transient absorption and fluorescence images. It can handle various light sources and optical configurations for diverse experimental setups.
Additional Specifications
The system supports the ORCA®-Flash4.0 V3 Digital CMOS camera and operates on Windows® 10 Pro, 64-bit. It uses Camera Link for interface and includes control and readout software HPD-TA. The data analyzer offers functions such as device control, data acquisition, profile function, data corrections, and axis calibration. Supported file formats include binary, TIFF, and ASCII.
Optics and Measurement
The optics for transient absorption measurement include white light input optics, excitation optics, and optical laser shutters. Measurements are accurate within a 250 nm to 750 nm wavelength range. The excitation optics use YAG laser mirrors with wavelengths of 266 nm, 355 nm, and 532 nm. Sample holders and laser shutters are also specified.
Light Source
The Xe light source is stable and operates without movement, covering a radiation wavelength range from 220 nm to 2000 nm. It has a power consumption of 150 W and features ozoneless quartz for window material. The light output stability is characterized by a drift of ±0.5%/h and a maximum fluctuation of 1.0%.
Additional Components
The system includes a computer set with software HPD-TA + Ta-Abs, a frame grabber board, DIO board, external trigger cable, shutter cable, and Camera Link cable. Dimensional outlines and weights for various components like the streak camera and spectrograph are also provided.
Contact Information
Contact details for Hamamatsu Photonics offices in various countries, including the USA, Germany, France, the UK, North Europe, Italy, China, and Taiwan, are provided.
Disclaimer
Specifications and external appearances are subject to change without notice, and product availability may vary based on local technical requirements and regulations.
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Catalog excerpts

Time-resolved absorption spectrum analysis system-1

Time-resolved absorption spectrum analysis system Measure the transient absorption spectrum in extremely short time ! Analysis of the formation and decay process of a reactive intermediate in a photoreaction in solutions, solids, membranes, etc are possible.

 Open the catalog to page 1
Time-resolved absorption spectrum analysis system-2

Measure the transient absorption spectrum in extremely short time in a high dynamic range with high S/N. The time-resolved absorption spectrum analysis system is a device to perform transient absorption spectrum measurements in extremely short time. This system enables to analyze the formation and decay process of a reactive intermediate in a photoreaction in solutions, solids, membranes, etc are possible. By using the streak camera as the detector and performing multiple-wavelengths time-resolved measurements with a single shot, time-resolved absorption spectra and transient absorption time-resolved...

 Open the catalog to page 2
Time-resolved absorption spectrum analysis system-3

General performance Nanosecond Q-SW YAG laser Temporal resolution Xe lamp Break down Measurement time range White light source Picosecond mode-lock YAG laser Measurement OD value Simultaneous observation wavelength width (W) and wavelength resolution (∆λ) Measurement wavelength range Number of channels 0.005 (for single shot, 0.02 or less) 100 gr/mm: W= 510 nm, ∆λ<3.0 nm 150 gr/mm: W= 340 nm, ∆λ<2.0 nm 300 gr/mm: W= 170 nm, ∆λ<1.0 nm 600 gr/mm: W= 85 nm, ∆λ<0.5 nm 250 nm to 750 nm Time axis: 1016 ch Wavelength axis: 1344 ch Functions The time-resolved absorption spectrum analyzing system is composed...

 Open the catalog to page 3
Time-resolved absorption spectrum analysis system-4

Operating principle Using a streak camera as the detector Sweep electrodes (electrons are swept in the direction from top to bottom) Sweep circuit Trigger signal Image intensifier Streak image on phosphor screen Lenses Light intensity Time Slit Space Phosphor screen MCP (electrons light) (which multiplies Accelerating electrons) The intensity of the incident light can be read from the brightness electrode of the phosphor screen, and the Streak tube (accelerates the electron) time and space from the position of the phosphor screen. Photocathode (photons electrons) Fig. 1 Operating principle of...

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Time-resolved absorption spectrum analysis system-5

Measurement example Measurement of transient absorption time-resolved spectrum -1 Time-resolved transient absorption spectral streak image of the triplet-triplet absorption of anthracene in supercritical carbon dioxide (40 ˚C, 10.9 MPa) Data courtesy of: National Institute of Advanced Industrial Science and Technology Supercritical Fluid Research Center (Sendai City, Japan) Researcher: Dr. Takafumi Aizawa Triplet-triplet absorption spectral of anthracene in supercritical carbone dioxide (40 ˚C, 10.9 MPa) Pressure dependency of the molar extinction coefficient of triplet anthracene (40 ˚C) Time-resolved...

 Open the catalog to page 5
Time-resolved absorption spectrum analysis system-6

Specifications High dynamic range streak camera C13410-01A The streak camera is an ultra high-speed detector with 5 ps temporal resolution. By combining with the spectrograph, transient absorption spectrums can be measured using with a single shot because multiple wavelengths can be observed simultaneously. The spectrograph is ideally suited for combination with the streak camera. Since an optical system that corrects for astigmatism is used, the light condensing efficiency at the detector is high and high-sensitivity measurements are possible. Streak tube Photocathode Spectral response Effective...

 Open the catalog to page 6
Time-resolved absorption spectrum analysis system-7

Optics for transient absorption measurement C13406-11 The optics for transient absorption measurement contains 3 kinds of optics: a white light input optics, an excitation optics, and 2 optical laser shutters. Measurements can be performed accurately in the 250 nm to 750 nm measurement wavelength range. Excitation optics is composed of 2 YAG laser mirrors with wavelength 266 nm, 355 nm, and 532 nm respectively. Measurement wavelength range 10 mm cell holder, 2 mm cell holder, Thin film sample holder Rotating solenoid, 2 heads (1 for pump light / 1 for probe light) Supported camera Component Dielectric...

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Time-resolved absorption spectrum analysis system-8

Dimensional outlines High dynamic range streak camera C13410-01A (Approx. 26 kg Main unit only) 40.5 ORCA®-Flash4.0 V3 Digital CMOS camera C13440-20CU (Approx. 2.2 kg) Optics for transient absorption measurement C13406-11 (Approx. 18 kg) ORCA is registered a trademark of Hamamatsu Photonics K.K. (China, France, Germany, Japan, U.K., U.S.A.) Windows is registered trademark of Microsoft Corporation in the U.S.A. Product and software package names noted in this documentation are trademarks or registered trademarks of their respective manufacturers. The university, institute, or company name of the...

 Open the catalog to page 8

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*Prices are pre-tax. They exclude delivery charges and customs duties and do not include additional charges for installation or activation options. Prices are indicative only and may vary by country, with changes to the cost of raw materials and exchange rates.