Specifications
Acrylic Acid (AA), also known as 2-Propenoic acid, is specified as a clear liquid at temperatures above 13°C. It has a maximum color of 10 APHA and a purity of at least 99.5% as determined by gas chromatography. The water content should not exceed 1000 ppm, and the dimer content is limited to 2000 ppm. The inhibitor content, specifically Monomethyl Ether of Hydroquinone (MEHQ), should be between 180 to 220 ppm.
Handling and Safety
It is crucial to avoid localized overheating above 25°C to prevent hazardous exothermic polymerization. Acrylic acid should not be stored for long periods due to dimer formation, which occurs at approximately 100 ppm daily at room temperature. The product remains within specifications for one month post-delivery.
Applications
Acrylic acid is used in a variety of applications including hydrosoluble agents, detergent auxiliaries, organic synthesis, copolymer emulsions for paints and inks, dispersions for textiles and adhesives, cleaning products, plastics, synthetic resins, and rubbers.
Main Physical Properties
The molecular weight is 72 g/mol, with a boiling point of 141°C and a freezing point of 13°C. It has a specific gravity of 1.05 g/mL at 20°C, a refractive index of 1.422, and a viscosity of 1.22 mPa.s. Acrylic acid is infinitely soluble in water at 20°C. Other properties include a specific heat of 2.05 kJ/kg°C, a latent heat of vaporization of 634 kJ/kg, and a heat of polymerization of 1077 kJ/kg. The flash point is 48.5°C, and the auto-ignition temperature is 438°C.
Packaging and Storage
Acrylic acid is delivered in stainless steel road tank cars or containers ranging from 25000 to 36000 liters. It should be stored at 15 to 25°C, away from light, and under an air atmosphere with at least 5% oxygen to activate the stabilizer. If crystallization occurs, it can be thawed safely by circulating tempered water up to 35°C through heating coils, ensuring proper mixing for even distribution of oxygen and inhibitor.
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