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Effects of oil temperature
on the solubility
In lubrication systems, the oil is
typically rather warm e.g.
+40…+60 °C. In situations when
temperature decreases considerable,
like when engines are turned off,
there is a risk of free water formation,
because the oil cannot anymore hold
the same amount of water. While the
absolute water content (ppm) has
remained unchanged, the saturation
point has been reached and the risk
of, for example, corrosion becomes
likely (see Figure 2).
In case free water has formed during
a shutdown, the oil should be dried
first or the system has to be started
carefully, running only the lubrication
system until normal operating
temperature is reached and the water
dissolves back into the oil. This
phenomenon can be monitored much
more easily with water activity
(Aw, see p. 3).
One should also consider that the hot
lubrication oil in the reservoir can
easily absorb more water if it is in
contact with ambient air. This kind of
long term "leak" will increase water
contamination in oil slowly.
Effects of oil ageing
on the solubility
The used oil's ability to hold water
is remarkably higher than a new
oil's. This is caused by the chemical
reactions that take place over the
life of the fluid changing the water
solubility. This is a very important
point to consider when oil is changed
or when new oil is added to existing
oil in the lubrication system.
Figure 3 demonstrates how the oil
ageing affects the water solubility
(saturation level 2000 vs 6000 ppm).
Figure 2 The effect of temperature on free water formation. The risk increases
when engines are switch off and temperature decreases. When the water
content reaches the saturation point free water starts to form.
Figure 3 The effect of oil ageing on its water solubility (water content in ppm
versus water activity reading). The test was at 40-47 °C with a new lubrication
oil and the same oil after 30 000 hours in service.
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