Catalogue OXITEC® Oxygen Analyser Systems
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Theory = Practice
ENOTEC goes for it with Nernst
Measuring oxygen using the zirconium oxide principle has been re­cognised a million times over as a simple and cost-efficient method for measuring oxygen in flue gases.
Configuration of the measuring cell
The technological and structural design of the OXITEC® zirconium oxide measuring cell guarantees permanent gas-tight separation
of process gas from reference gas.
ENOTEC has resolutely put the Nernst equation
into practice for the user's benefit.
The Nernst equation and its "leak-tight fraction line".
A process gas (A) with an unknown oxygen (02) concentration flows around the outside of a measuring probe which is sealed off to the process gas by means of a heated zirconium-oxide measuring cell (B). A reference gas (C), with a known oxygen (02) concentration, flows to the inside of the measuring cell.
At an optimum temperature a voltage (U) in mV is created between the two surfaces of the cell. At a constant temperature in the cell this voltage is dependent only on the ratio of the oxygen concen­trations (partial pressures) in (A) and (C). Using air (oxygen content at constant 20.95%) as a reference gas, the measured voltage is a direct measure of the oxygen concentra­tion in the process gas (A), provided that the isolation between the process gas and the reference gas is absolutely gas-tight, thus ruling out distortion of the resulting measured value.
Ion-migration
Solder
Zirconium--oxid (B)
Heating Electrodes
Thermo­couple
Reference gas n (Air)(C) 1}
Only industrial probes manufactured by ENOTEC truly comply with the Nernst equation.
Tlog-j^ + C
U = K
Process gas with partial pressure P2
U = measurable voltage (mV)
K = natural constant
T = temperature (measuring cell)
P1 = 02 - partial pressure in the reference gas
P2 = 02 - partial pressure in the process gas
C = constant offset
With a "leak-tight fraction line" and air as the reference gas, all parameters in the Nernst equation - except for P2 - are constant. This means that the mV signal is dependent only on the 02 partial
pressure (P2) in the process gas.
The Nernst equation therefore does not require calibration
Thanks to the special soldering technique used in their manufacture, only OXITEC® probes guarantee the leak-tight fraction line.
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