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DuPont™ Capstone™ 4-I is a versatile fluorinated iodide useful
in preparing repellent and surfactant products. It is based on
four fluorinated carbon molecules that cannot break down
to PFOA in the environment. Capstone™ 4-I is part of a large
family of fluorinated specialty monomers offered by DuPont.
For information on other Capstone™ monomers, use the contact
information below.
Specifications
Property Limit, wt%
Perfluorobutyliodide 90 min
Perfluoroethyliodide 2.0 max
Perfluorohexyliodide 1.0 max
Perfluorohexane 8.5 max
Perfluorooctane 1.0 max
Uses
Capstone™ 4-I is a short-chain perfluorinated monomer useful
in producing repellents, lubricants and surfactants. The
perfluoroalkyl group of Capstone™ 4-I can provide formulations
with lower surface energy, improved chemical stability and
surface lubricity, and enhanced molecular orientation.
In addition, Capstone™ 4-I can be oxidized to the acid fluoride
and converted to carboxylic acid derivatives through hydrolysis.
It can add across olefins or initiate telomerization reactions.
Following are specific uses for Capstone™ 4-I:
Surfactants
• Sulfinic and sulfonic acids as surfactants and detergents
(US4866190)
• Surfactants for liquid or supercritical carbon dioxide reactions
(JP2003238473)
• Aromatic sulfates as surfactants (JP2001097943, US5491257)
• Tertiary perfluoroalkoxide surfactants in PTFE dispersion
polymerization (US4564661)
Lubricants
• Fluorocarbon waxes (US3956000)
• Phosphines as oil additives (DE2110769)
• Spirobiindane derivatives as oil additives (JP3824339)
• Fluoroalkylsilanes as hydraulic fluids (US5196614)
• Carboxylate salts as antiwear additives (US5202038)
• Carboxylic ester or amide for magnetic recording media
(JP09104881)
Liquid Crystalline Materials and Devices
• Esters (JP2003201274)
• Biphenyls (WO2003040074, JP06056703)
• Fluorosilanes (US6737124)
• Hybrid polymers (US6919404)
• Polyimides, polyamic acids, and poly(amide esters)
(US6194039)
• Benzylideneanilines (JP04069372)
Medical and Biological Applications
• Steroids (US7148213, US5719159, WO9313123)
• Peptidyl perfluoroalkyl ketones as inhibitors of elastase
(US6008196)
• Carboxamides as surfactant intermediates and as drugs
(FR2623497)
• Triazole antifungal agents (US4727159)
• Hydroximic acid derivatives as pesticides (WO9967209)
• Phthalamides as insecticides (WO2005095351)
• Perfluoroalkylanilines for insecticides (US6717013)
• Anilide derivatives as agricultural chemicals (WO2002096882)
• Fluorinated polysiloxanes for cosmetics (JP09291010,
JP09104757, JP3558410)
• Perfluorocarbon emulsions as blood substitutes
(US2004057906)
• Modified lipids for drug delivery systems (US6090800,
US6537246)
• Optoacoustic contrast agents for medical diagnostics
(US6123923)
• Cosmetic skin or hair care compositions (US5851544)
• Prodrugs comprising fluorinated amphiphiles or steroids
(WO9850041)
• Surfactant for perfluorocarbon microemulsions for blood
substitutes (US4975468)
Repellent Coatings
• Arylguanamine derivatives as water and oil repellents for
textiles (JP03145477)
• Perfluoroalkylphenol stain resists for synthetic polymer fibers
(WO2002055464)
• Fluoroalkyl triazines as water repellent (US6391948)
• Urethanes for water- and oil-repellents (WO006013791)
• Fluorinated polyurethanes as soil-relase finishes for textiles
(US3872058)
CF3CF2CF2CF2—I
DuPont™ Capstone™ 4-I
PERFLUOROBUTYL IODIDE, 1-IODOPERFLUOROBUTANE
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