General Lab Catalogue - Crison Instruments - #5

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Text version of the page
Introduction
The interaction between the sample, the sensor and the measuring Instrument gives an electrometrlc measure­ment.
However, a correct result depends on the technician us­ing the equipment, who must consider aspects such as:
- how the sample was taken.
- the choice of an appropriate sensor, ensuring that It has been correctly maintained.
- the use of a stirrer.
- etc.
In this catalogue we offer sensors, Instruments, accessories and even guidelines for the users of our equipment.
Sensors
We offer sensors which measure:
- Ion activity, e.g. pH, chloride, fluoride, etc.
- Redox: capacltyfor oxidation and reduction
- Ionic mobility, conductivity
- Partial DO pressure.
- Temperature.
Measuring methods
Potentiometry
Measurement ofthe potential produced by a pair of electrodes, the Indicator and the reference, In a specific solution.
Examples: measurement of pH and redox. Titration Is simply the analysis of the variations In potential which a specific substance undergoes when another, known as a titrate, Is added.
Bipotentiometry
Measurement ofthe potential read by a platinum double electrode to which a constant current Is applied. Example: Karl Flshervolumetrlctltratlon.
Conductivity
Measurement of Ion mobility In a solution. An electrical field between two electrodes Is applied to measure It. The anions migrate towards one of them and the cations towards the other.
To prevent changes occurring In the substances, or the deposit of a layer on the electrodes, etc., alternating current Is used.
Amperometry
This measures the current produced In the cathode of an electrode, thanks to the presence of the element to be measured.
Used In DO measurement.
Temperature measurement
Temperature can be measured either as an Independent parameter, or as data to be taken Into account when measuring pH, conductivity, etc. With aPtlOO or Pt 1000 probe, the sensor Is a resistance which varies depending on the temperature. A pair of metals, or thermopar, which generate a temperature-related potential, may also be used.
Liquids dispensing
Burettes
The basic requlrementfor dispensing liquids Is a high-precision mechanism, actloned by an electronically-controlled step motor. Thanks to the high number of steps Into which the length of the syringe plunger Is subdivided, dispensations of amounts of less than 1 pi per step can be achieved.
Apartfrom doslfylng liquids, burettes can also be used In the various methods of titration.
Method
Sensor
Instrument
Potentiometry
pH electrode
pH-meter
Redox electrode
pH-meter-burette
Selective
Titrator
electrode, ISE
Bipotentiometry
Double Pt
electrode
Conductometry
Conductivity
Conductivity
cell
meter
Amperometry
D.O.
Oxymeter
electrode
Temperature
Probe:
Thermometer
measurement
-Pt1000
pH-meter
-thermocouple
Conductivity meter
Liquids dispensing
Burette
pH-meter-burette
Titration
pH electrode
Titrator
Metallic electrode
Laboratory Catalogue 2004 1st Edition

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