Catalogue Characteristics & Compatibility of Thermoplastics for Ultrasonic Welding
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Polymers: Characteristics and Compatibility for Ultrasonic Assembly
Technical information PW-1
Weldability of Polymers
The principle of ultrasonic assembly involves the use of high-frequency mechanical vibrations transmitted through thermoplastic parts to generate a frictional heat build-up at an interface. This bulletin provides guidelines on the welding characteristics of thermo­plastics as well as an understanding of how polymer structure and other factors affect the weldability of various polymers. The term "weldability" is used generically and includes the ability to stake, swage, insert, or spot weld the resin.
Polymers: Thermoset Versus Thermoplastic
A polymer is a repeating structural unit formed dur­ing a process called polymerization. There are two basic polymer families: thermoset and thermoplastic. A thermoset is a material that, once formed, under­goes an irreversible chemical change and cannot be reformed with the reintroduction of heat and pres­sure; therefore, thermosets cannot be ultrasonically assembled in the traditional sense. A thermoplastic material, after being formed can, with the reintro­duction of heat and pressure, be remelted and reformed, undergoing only a change of state. This characteristic makes thermoplastics suitable for ultra­sonic assembly.
All the information contained in this information sheet and others covering ultrasonic processes is based on the use of thermoplastic polymers (resins).
Factors That Affect Weldability
When discussing the weldability of thermoplastics, it must be recognized that there are a number of factors that affect the ultrasonic energy requirements and, therefore, weldability of the various resins. The major factors include polymer structure, melt temperature, melt index (flow), modulus of elasticity (stiffness), and chemical makeup.
Polymer Structure
Amorphous polymers have a structure characterized by a random molecular arrangement (Figure 1a).
Specific Heat vs. Temperature
Semi-Crystalline
Specific Heat
Amorphous
2
Temp
They have a broad softening temperature (Tg, glass transition temperature) range (Figure 2) that allows the material to soften gradually, melt and flow with­out prematurely solidifying. These polymers generally are very efficient with regard to their ability to trans­mit ultrasonic vibrations, and can be welded under a wide range of force/amplitude combinations.
Semi-crystalline polymers are characterized by regions of orderly molecular arrangement (Figure 1b). They have sharp melting (Tm, melt temperature) and re­solidification points (Figure 2). The molecules of the polymer, when in the solid state, are spring-like and internally absorb a percentage of the high-frequency mechanical vibrations, thus making it more difficult to transmit the ultrasonic energy to the joint inter­face. For this reason, high amplitude is usually required. The sharp melting point is the result of a very high energy requirement (high heat of fusion) necessary to break down the semi-crystalline struc­ture to allow material flow. Once the molten material leaves the heated area, these resins solidify rapidly with only a small reduction in temperature. These characteristics therefore warrant special consideration (i.e., higher amplitude, careful attention to joint design, horn contact, distance to the weld joint, and fixturing) to obtain successful results.
Melt Temperature
The higher the melt temperature of a polymer, the more ultrasonic energy is required for welding.
Stiffness (Modulus of Elasticity)
The stiffness of the polymer to be welded will influ­ence its ability to transmit the ultrasonic energy to the joint interface. Generally the stiffer a material the better its transmission capability.
Welding Dissimilar Resins
A similar melt temperature between the materials to be welded is a basic requirement for successful weld­ing of rigid parts, because a temperature difference of 40oF (22oC) can be sufficient enough to hinder weld-
Applied Technologies Group
41 Eagle Road Danbury, CT 06813-1961 (203) 796-0349 fax (203) 796-9838 email: info@bran-sonultrasonics.com
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